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| 1st(1st leg) | Club Nacional | - | Arsenal de Sarandí | 1:0 (1:0) | ||
| 2nd (2nd leg) | Arsenal de Sarandí | - | Club Nacional | 0:0 (0:0) | ||
| 1st(1st leg): 07/05/2014 23:45 | 2nd (2nd leg): 14/05/2014 23:30 | Winner: Club Nacional | ||||
| 1st(1st leg) | San Lorenzo | - | Cruzeiro | 1:0 (0:0) | ||
| 2nd (2nd leg) | Cruzeiro | - | San Lorenzo | 1:1 (0:1) | ||
| 1st(1st leg): 08/05/2014 02:00 | 2nd (2nd leg): 15/05/2014 02:00 | Winner: San Lorenzo | ||||
| 1st(1st leg) | Lanús | - | Bolívar | 1:1 (1:0) | ||
| 2nd (2nd leg) | Bolívar | - | Lanús | 1:0 (0:0) | ||
| 1st(1st leg): 08/05/2014 23:45 | 2nd (2nd leg): 15/05/2014 23:30 | Winner: Bolívar | ||||
| 1st(1st leg) | Atlético Nacional | - | Defensor Sporting | 0:2 (0:0) | ||
| 2nd (2nd leg) | Defensor Sporting | - | Atlético Nacional | 1:0 (0:0) | ||
| 1st(1st leg): 09/05/2014 02:00 | 2nd (2nd leg): 16/05/2014 02:00 | Winner: Defensor Sporting | ||||
