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| 1st(1st leg) | Ceará - CE | - | São Paulo FC | 2:1 (1:1) | ||
| 2nd (2nd leg) | São Paulo FC | - | Ceará - CE | 3:0 (0:0) | ||
| 1st(1st leg): 10/08/2011 23:30 | 2nd (2nd leg): 25/08/2011 01:50 | Winner: São Paulo FC | ||||
| 1st(1st leg) | Atlético Mineiro | - | Botafogo - RJ | 1:2 (1:2) | ||
| 2nd (2nd leg) | Botafogo - RJ | - | Atlético Mineiro | 1:0 (1:0) | ||
| 1st(1st leg): 11/08/2011 01:50 | 2nd (2nd leg): 24/08/2011 00:15 | Winner: Botafogo - RJ | ||||
| 1st(1st leg) | Flamengo RJ | - | Athletico Paranaense | 1:0 (0:0) | ||
| 2nd (2nd leg) | Athletico Paranaense | - | Flamengo RJ | 0:1 (0:0) | ||
| 1st(1st leg): 11/08/2011 01:50 | 2nd (2nd leg): 25/08/2011 01:50 | Winner: Flamengo RJ | ||||
| 1st(1st leg) | Vasco da Gama - RJ | - | Palmeiras | 2:0 (1:0) | ||
| 2nd (2nd leg) | Palmeiras | - | Vasco da Gama - RJ | 3:1 (1:0) | ||
| 1st(1st leg): 12/08/2011 01:50 | 2nd (2nd leg): 26/08/2011 00:15 | Winner: Vasco da Gama - RJ | ||||
| 1st(1st leg) | Club Nacional | - | Club Aurora | 1:1 (0:1) | ||
| 2nd (2nd leg) | Club Aurora | - | Club Nacional | 5:2 (3:2) | ||
| 1st(1st leg): 30/08/2011 23:00 | 2nd (2nd leg): 20/09/2011 23:15 | Winner: Club Aurora | ||||
| 1st(1st leg) | Arsenal de Sarandí | - | Estudiantes | 2:0 (0:0) | ||
| 2nd (2nd leg) | Estudiantes | - | Arsenal de Sarandí | 1:0 (0:0) | ||
| 1st(1st leg): 31/08/2011 01:15 | 2nd (2nd leg): 07/09/2011 01:15 | Winner: Arsenal de Sarandí | ||||
| 1st(1st leg) | Lanús | - | Godoy Cruz | 2:2 (1:2) | ||
| 2nd (2nd leg) | Godoy Cruz | - | Lanús | 0:0 (0:0) | ||
| 1st(1st leg): 01/09/2011 01:15 | 2nd (2nd leg): 08/09/2011 01:45 | Winner: Godoy Cruz | ||||
| 1st(1st leg) | Argentinos Juniors | - | Vélez Sarsfield | 0:0 (0:0) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | Argentinos Juniors | 4:0 (1:0) | ||
| 1st(1st leg): 02/09/2011 00:15 | 2nd (2nd leg): 08/09/2011 23:15 | Winner: Vélez Sarsfield | ||||
| 1st(1st leg) | Deportivo Anzoátegui | - | Universitario de Deportes | 1:2 (0:1) | ||
| 2nd (2nd leg) | Universitario de Deportes | - | Deportivo Anzoátegui | 2:0 (0:0) | ||
| 1st(1st leg): 02/09/2011 02:45 | 2nd (2nd leg): 14/09/2011 23:15 | Winner: Universitario de Deportes | ||||
| 1st(1st leg) | Universidad Católica | - | Deportes Iquique | 2:1 (1:0) | ||
| 2nd (2nd leg) | Deportes Iquique | - | Universidad Católica | 0:0 (0:0) | ||
| 1st(1st leg): 09/09/2011 01:45 | 2nd (2nd leg): 15/09/2011 01:50 | Winner: Universidad Católica | ||||
| 1st(1st leg) | LDU Quito | - | Trujillanos FC | 4:1 (2:1) | ||
| 2nd (2nd leg) | Trujillanos FC | - | LDU Quito | 0:1 (0:1) | ||
| 1st(1st leg): 13/09/2011 23:00 | 2nd (2nd leg): 23/09/2011 00:15 | Winner: LDU Quito | ||||
| 1st(1st leg) | Universidad de Chile | - | Nacional | 1:0 (0:0) | ||
| 2nd (2nd leg) | Nacional | - | Universidad de Chile | 0:2 (0:2) | ||
| 1st(1st leg): 14/09/2011 01:15 | 2nd (2nd leg): 21/09/2011 23:15 | Winner: Universidad de Chile | ||||
| 1st(1st leg) | La Equidad | - | Libertad | 0:1 (0:0) | ||
| 2nd (2nd leg) | Libertad | - | La Equidad | 1:0 (1:0) | ||
| 1st(1st leg): 14/09/2011 03:30 | 2nd (2nd leg): 22/09/2011 01:45 | Winner: Libertad | ||||
| 1st(1st leg) | Club Olimpia | - | Emelec | 2:1 (1:1) | ||
| 2nd (2nd leg) | Emelec | - | Club Olimpia | 1:2 (0:2) | ||
| 1st(1st leg): 16/09/2011 00:15 | 2nd (2nd leg): 21/09/2011 01:45 | Winner: Club Olimpia | ||||
| 1st(1st leg) | Santa Fe | - | Deportivo Cali | 1:1 (0:0) | ||
| 2nd (2nd leg) | Deportivo Cali | - | Santa Fe | 5:6 (1:0, 1:1, 1:1) pso | ||
| 1st(1st leg): 16/09/2011 02:45 | 2nd (2nd leg): 23/09/2011 02:45 | Winner: Santa Fe | ||||
