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| 1st(1st leg) | Lanús | - | Universidad de Chile | 4:0 (3:0) | ||
| 2nd (2nd leg) | Universidad de Chile | - | Lanús | 1:0 (0:0) | ||
| 1st(1st leg): 19/09/2013 00:15 | 2nd (2nd leg): 25/09/2013 23:30 | Winner: Lanús | ||||
| 1st(1st leg) | La Equidad | - | Vélez Sarsfield | 1:2 (0:0) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | La Equidad | 2:1 (0:1) | ||
| 1st(1st leg): 19/09/2013 02:30 | 2nd (2nd leg): 03/10/2013 01:15 | Winner: Vélez Sarsfield | ||||
| 1st(1st leg) | Liga de Loja | - | River Plate | 2:1 (1:0) | ||
| 2nd (2nd leg) | River Plate | - | Liga de Loja | 2:0 (1:0) | ||
| 1st(1st leg): 20/09/2013 01:15 | 2nd (2nd leg): 26/09/2013 23:30 | Winner: River Plate | ||||
| 1st(1st leg) | Coritiba - PR | - | Itagüi Ditaires | 0:1 (0:0) | ||
| 2nd (2nd leg) | Itagüi Ditaires | - | Coritiba - PR | 2:1 (0:1) | ||
| 1st(1st leg): 25/09/2013 01:00 | 2nd (2nd leg): 25/10/2013 02:00 | Winner: Itagüi Ditaires | ||||
| 1st(1st leg) | Ponte Preta | - | Deportivo Pasto | 2:0 (1:0) | ||
| 2nd (2nd leg) | Deportivo Pasto | - | Ponte Preta | 1:0 (0:0) | ||
| 1st(1st leg): 25/09/2013 23:30 | 2nd (2nd leg): 23/10/2013 01:15 | Winner: Ponte Preta | ||||
| 1st(1st leg) | Libertad | - | Sport Recife - PE | 2:0 (2:0) | ||
| 2nd (2nd leg) | Sport Recife - PE | - | Libertad | 1:2 (0:1) | ||
| 1st(1st leg): 26/09/2013 01:50 | 2nd (2nd leg): 24/10/2013 01:10 | Winner: Libertad | ||||
| 1st(1st leg) | São Paulo FC | - | Universidad Católica | 1:1 (1:1) | ||
| 2nd (2nd leg) | Universidad Católica | - | São Paulo FC | 3:4 (2:2) | ||
| 1st(1st leg): 27/09/2013 02:00 | 2nd (2nd leg): 24/10/2013 00:50 | Winner: São Paulo FC | ||||
| 1st(1st leg) | Atlético Nacional | - | Bahia - BA | 1:0 (1:0) | ||
| 2nd (2nd leg) | Bahia - BA | - | Atlético Nacional | 3:4 (1:0, 1:0, 1:0) pso | ||
| 1st(1st leg): 27/09/2013 02:00 | 2nd (2nd leg): 24/10/2013 23:30 | Winner: Atlético Nacional | ||||
