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| 1st(1st leg) | SD Compostela | - | UE Lleida | 1:2 (1:1) | ||
| 2nd (2nd leg) | UE Lleida | - | SD Compostela | 4:1 (2:1) | ||
| 1st(1st leg): 10/10/1993 | 2nd (2nd leg): 02/11/1993 | Winner: UE Lleida | ||||
| 1st(1st leg) | CP Mérida | - | Rayo Vallecano | 1:0 (0:0) | ||
| 2nd (2nd leg) | Rayo Vallecano | - | CP Mérida | 1:1 (0:0) | ||
| 1st(1st leg): 12/10/1993 | 2nd (2nd leg): 14/11/1993 | Winner: CP Mérida | ||||
| 1st(1st leg) | Almería CF | - | Espanyol Barcelona | 0:2 (0:0) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | Almería CF | 5:1 (3:0) | ||
| 1st(1st leg): 21/10/1993 | 2nd (2nd leg): 03/11/1993 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | Cádiz CF | - | Real Oviedo | 0:2 (0:0) | ||
| 2nd (2nd leg) | Real Oviedo | - | Cádiz CF | 4:0 (2:0) | ||
| 1st(1st leg): 26/10/1993 | 2nd (2nd leg): 13/11/1993 | Winner: Real Oviedo | ||||
| 1st(1st leg) | Athletic Bilbao | - | Real Zaragoza | 0:2 (0:1) | ||
| 2nd (2nd leg) | Real Zaragoza | - | Athletic Bilbao | 1:1 (1:0) | ||
| 1st(1st leg): 27/10/1993 | 2nd (2nd leg): 04/11/1993 | Winner: Real Zaragoza | ||||
| 1st(1st leg) | Talavera CF | - | Racing Santander | 2:0 (1:0) | ||
| 2nd (2nd leg) | Racing Santander | - | Talavera CF | 3:2 (0:0) | ||
| 1st(1st leg): 27/10/1993 | 2nd (2nd leg): 03/11/1993 | Winner: Talavera CF | ||||
| 1st(1st leg) | Palamós CF | - | CD Toledo | 0:0 | ||
| 2nd (2nd leg) | CD Toledo | - | Palamós CF | 1:0 | ||
| 1st(1st leg): 27/10/1993 | 2nd (2nd leg): 03/11/1993 | Winner: CD Toledo | ||||
| 1st(1st leg) | Elche CF | - | Real Betis | 2:1 (0:1) | ||
| 2nd (2nd leg) | Real Betis | - | Elche CF | 5:0 (3:0) | ||
| 1st(1st leg): 27/10/1993 | 2nd (2nd leg): 04/11/1993 | Winner: Real Betis | ||||
| 1st(1st leg) | Real Murcia | - | Real Valladolid | 0:3 (0:2) | ||
| 2nd (2nd leg) | Real Valladolid | - | Real Murcia | 3:1 (2:1) | ||
| 1st(1st leg): 27/10/1993 | 2nd (2nd leg): 14/11/1993 | Winner: Real Valladolid | ||||
| 1st(1st leg) | Hércules CF | - | Real Sociedad | 1:1 (1:1) | ||
| 2nd (2nd leg) | Real Sociedad | - | Hércules CF | 0:0 (0:0) | ||
| 1st(1st leg): 27/10/1993 | 2nd (2nd leg): 03/11/1993 | Winner: Real Sociedad | ||||
| 1st(1st leg) | RC Celta | - | Albacete | 4:0 (2:0) | ||
| 2nd (2nd leg) | Albacete | - | RC Celta | 4:1 (1:1) | ||
| 1st(1st leg): 27/10/1993 | 2nd (2nd leg): 04/11/1993 | Winner: RC Celta | ||||
| 1st(1st leg) | Polideportivo Ejido | - | UD Salamanca | 3:0 | ||
| 2nd (2nd leg) | UD Salamanca | - | Polideportivo Ejido | 4:1 aet | ||
| 1st(1st leg): 27/10/1993 | 2nd (2nd leg): 04/11/1993 | Winner: Polideportivo Ejido | ||||
| 1st(1st leg) | Getafe CF | - | CD Logroñés | 0:1 (0:0) | ||
| 2nd (2nd leg) | CD Logroñés | - | Getafe CF | 2:1 (2:0) | ||
| 1st(1st leg): 27/10/1993 | 2nd (2nd leg): 04/11/1993 | Winner: CD Logroñés | ||||
| 1st(1st leg) | CD Castellón | - | Sevilla FC | 2:0 (2:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | CD Castellón | 3:0 (1:0, 2:0) aet | ||
| 1st(1st leg): 16/11/1993 | 2nd (2nd leg): 24/11/1993 | Winner: Sevilla FC | ||||
