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| 1st(1st leg) | Sporting Gijón | - | FC Barcelona | 0:3 (0:3) | ||
| 2nd (2nd leg) | FC Barcelona | - | Sporting Gijón | 1:1 (1:1) | ||
| 1st(1st leg): 04/01/1994 19:30 | 2nd (2nd leg): 12/01/1994 19:45 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Real Madrid | - | Atlético Madrid | 2:2 (1:1) | ||
| 2nd (2nd leg) | Atlético Madrid | - | Real Madrid | 2:3 (1:1) | ||
| 1st(1st leg): 04/01/1994 20:00 | 2nd (2nd leg): 13/01/1994 20:30 | Winner: Real Madrid | ||||
| 1st(1st leg) | Deportivo La Coruña | - | Real Oviedo | 1:3 (0:3) | ||
| 2nd (2nd leg) | Real Oviedo | - | Deportivo La Coruña | 0:1 (0:1) | ||
| 1st(1st leg): 05/01/1994 19:30 | 2nd (2nd leg): 12/01/1994 19:15 | Winner: Real Oviedo | ||||
| 1st(1st leg) | Espanyol Barcelona | - | Sevilla FC | 0:1 (0:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | Espanyol Barcelona | 2:2 (1:1) | ||
| 1st(1st leg): 05/01/1994 19:45 | 2nd (2nd leg): 12/01/1994 20:00 | Winner: Sevilla FC | ||||
| 1st(1st leg) | CD Logroñés | - | RC Celta | 1:0 (1:0) | ||
| 2nd (2nd leg) | RC Celta | - | CD Logroñés | 4:3 (1:0, 1:0, 1:0) pso | ||
| 1st(1st leg): 05/01/1994 20:00 | 2nd (2nd leg): 12/01/1994 20:00 | Winner: RC Celta | ||||
| 1st(1st leg) | CD Tenerife | - | Valencia CF | 3:1 (2:0) | ||
| 2nd (2nd leg) | Valencia CF | - | CD Tenerife | 3:2 (2:0) | ||
| 1st(1st leg): 05/01/1994 21:00 | 2nd (2nd leg): 12/01/1994 20:00 | Winner: CD Tenerife | ||||
| 1st(1st leg) | Real Betis | - | CP Mérida | 3:1 (1:0) | ||
| 2nd (2nd leg) | CP Mérida | - | Real Betis | 1:1 (0:0) | ||
| 1st(1st leg): 06/01/1994 16:00 | 2nd (2nd leg): 12/01/1994 20:00 | Winner: Real Betis | ||||
| 1st(1st leg) | CD Badajoz | - | Real Zaragoza | 1:0 (1:0) | ||
| 2nd (2nd leg) | Real Zaragoza | - | CD Badajoz | 3:0 (2:0) | ||
| 1st(1st leg): 06/01/1994 16:00 | 2nd (2nd leg): 12/01/1994 19:45 | Winner: Real Zaragoza | ||||
