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| 1st(1st leg) | CE Sant Gabriel | - | Prainsa | 3:3 | ||
| 2nd (2nd leg) | Prainsa | - | CE Sant Gabriel | 1:1 | ||
| 1st(1st leg): 12/05/2013 | 2nd (2nd leg): 19/05/2013 | Winner: Prainsa | ||||
| 1st(1st leg) | Espanyol Barcelona | - | Levante UD | 1:1 | ||
| 2nd (2nd leg) | Levante UD | - | Espanyol Barcelona | 2:1 | ||
| 1st(1st leg): 12/05/2013 | 2nd (2nd leg): 18/05/2013 | Winner: Levante UD | ||||
| 1st(1st leg) | Rayo Vallecano | - | FC Barcelona | 0:0 | ||
| 2nd (2nd leg) | FC Barcelona | - | Rayo Vallecano | 2:0 aet | ||
| 1st(1st leg): 12/05/2013 | 2nd (2nd leg): 19/05/2013 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Atlético Madrid | - | Athletic Bilbao | 1:0 | ||
| 2nd (2nd leg) | Athletic Bilbao | - | Atlético Madrid | 1:1 | ||
| 1st(1st leg): 12/05/2013 | 2nd (2nd leg): 19/05/2013 | Winner: Atlético Madrid | ||||
