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| 1st(1st leg) | Metalist Kharkiv | - | Olympiakos Piraeus | 0:1 (0:0) | ||
| 2nd (2nd leg) | Olympiakos Piraeus | - | Metalist Kharkiv | 1:2 (1:0) | ||
| 1st(1st leg): 08/03/2012 18:00 | 2nd (2nd leg): 15/03/2012 20:05 | Winner: Metalist Kharkiv | ||||
| 1st(1st leg) | Sporting CP | - | Manchester City | 1:0 (0:0) | ||
| 2nd (2nd leg) | Manchester City | - | Sporting CP | 3:2 (0:2) | ||
| 1st(1st leg): 08/03/2012 18:00 | 2nd (2nd leg): 15/03/2012 20:05 | Winner: Sporting CP | ||||
| 1st(1st leg) | FC Twente | - | FC Schalke 04 | 1:0 (0:0) | ||
| 2nd (2nd leg) | FC Schalke 04 | - | FC Twente | 4:1 (1:1) | ||
| 1st(1st leg): 08/03/2012 18:00 | 2nd (2nd leg): 15/03/2012 20:05 | Winner: FC Schalke 04 | ||||
| 1st(1st leg) | Atlético Madrid | - | Beşiktaş | 3:1 (3:0) | ||
| 2nd (2nd leg) | Beşiktaş | - | Atlético Madrid | 0:3 (0:1) | ||
| 1st(1st leg): 08/03/2012 18:00 | 2nd (2nd leg): 15/03/2012 20:05 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | Standard Liège | - | Hannover 96 | 2:2 (2:1) | ||
| 2nd (2nd leg) | Hannover 96 | - | Standard Liège | 4:0 (2:0) | ||
| 1st(1st leg): 08/03/2012 20:05 | 2nd (2nd leg): 15/03/2012 18:00 | Winner: Hannover 96 | ||||
| 1st(1st leg) | Valencia CF | - | PSV Eindhoven | 4:2 (3:0) | ||
| 2nd (2nd leg) | PSV Eindhoven | - | Valencia CF | 1:1 (0:0) | ||
| 1st(1st leg): 08/03/2012 20:05 | 2nd (2nd leg): 15/03/2012 18:00 | Winner: Valencia CF | ||||
| 1st(1st leg) | AZ Alkmaar | - | Udinese Calcio | 2:0 (0:0) | ||
| 2nd (2nd leg) | Udinese Calcio | - | AZ Alkmaar | 2:1 (2:1) | ||
| 1st(1st leg): 08/03/2012 20:05 | 2nd (2nd leg): 15/03/2012 18:00 | Winner: AZ Alkmaar | ||||
| 1st(1st leg) | Manchester United | - | Athletic Bilbao | 2:3 (1:1) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | Manchester United | 2:1 (1:0) | ||
| 1st(1st leg): 08/03/2012 20:05 | 2nd (2nd leg): 15/03/2012 18:00 | Winner: Athletic Bilbao | ||||
