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| 1st(1st leg) | Fostiras FC | - | Panionios GSS | 1:0 (1:0) | ||
| 2nd (2nd leg) | Panionios GSS | - | Fostiras FC | 2:1 (2:0) | ||
| 1st(1st leg): 28/11/2012 12:30 | 2nd (2nd leg): 19/12/2012 18:00 | Winner: Fostiras FC | ||||
| 1st(1st leg) | Levadiakos | - | Pierikos Katerini | 2:0 (1:0) | ||
| 2nd (2nd leg) | Pierikos Katerini | - | Levadiakos | 0:5 (0:2) | ||
| 1st(1st leg): 28/11/2012 16:30 | 2nd (2nd leg): 20/12/2012 18:00 | Winner: Levadiakos | ||||
| 1st(1st leg) | OFI Heraklion | - | Apollon Smyrnis | 1:0 (0:0) | ||
| 2nd (2nd leg) | Apollon Smyrnis | - | OFI Heraklion | 2:0 (1:0, 1:0) aet | ||
| 1st(1st leg): 28/11/2012 16:30 | 2nd (2nd leg): 22/12/2012 15:00 | Winner: Apollon Smyrnis | ||||
| 1st(1st leg) | Olympiakos Piraeus | - | Panachaiki GE | 2:0 (0:0) | ||
| 2nd (2nd leg) | Panachaiki GE | - | Olympiakos Piraeus | 0:3 dec. | ||
| 1st(1st leg): 28/11/2012 18:30 | 2nd (2nd leg): 19/12/2012 18:00 | Winner: Olympiakos Piraeus | ||||
| 1st(1st leg) | Tyrnavos FC | - | AO Kerkyra | 0:2 (0:1) | ||
| 2nd (2nd leg) | AO Kerkyra | - | Tyrnavos FC | 0:0 (0:0) | ||
| 1st(1st leg): 29/11/2012 12:30 | 2nd (2nd leg): 20/12/2012 15:00 | Winner: AO Kerkyra | ||||
| 1st(1st leg) | Panthrakikos | - | Niki Volou FC | 2:0 (1:0) | ||
| 2nd (2nd leg) | Niki Volou FC | - | Panthrakikos | 1:1 (0:0) | ||
| 1st(1st leg): 29/11/2012 16:30 | 2nd (2nd leg): 19/12/2012 15:00 | Winner: Panthrakikos | ||||
| 1st(1st leg) | Panathinaikos | - | AO Proodeftiki | 4:0 (2:0) | ||
| 2nd (2nd leg) | AO Proodeftiki | - | Panathinaikos | 1:2 (1:0) | ||
| 1st(1st leg): 29/11/2012 16:30 | 2nd (2nd leg): 19/12/2012 12:00 | Winner: Panathinaikos | ||||
| 1st(1st leg) | PAS Giannina | - | Panserraikos | 1:0 (1:0) | ||
| 2nd (2nd leg) | Panserraikos | - | PAS Giannina | 0:2 (0:1) | ||
| 1st(1st leg): 29/11/2012 18:30 | 2nd (2nd leg): 23/12/2012 18:00 | Winner: PAS Giannina | ||||
| 1st(1st leg) | Veria FC | - | Thrasyvoulos Fylis | 0:0 (0:0) | ||
| 2nd (2nd leg) | Thrasyvoulos Fylis | - | Veria FC | 0:2 (0:1) | ||
| 1st(1st leg): 12/12/2012 16:30 | 2nd (2nd leg): 20/12/2012 15:00 | Winner: Veria FC | ||||
| 1st(1st leg) | GS Kallithea | - | Aris Saloniki | 3:1 (1:0) | ||
| 2nd (2nd leg) | Aris Saloniki | - | GS Kallithea | 2:1 (1:0) | ||
| 1st(1st leg): 12/12/2012 16:30 | 2nd (2nd leg): 23/12/2012 18:00 | Winner: GS Kallithea | ||||
| 1st(1st leg) | Olympiakos Volou | - | Atromitos | 1:1 (1:0) | ||
| 2nd (2nd leg) | Atromitos | - | Olympiakos Volou | 2:2 (1:0) | ||
| 1st(1st leg): 12/12/2012 18:30 | 2nd (2nd leg): 22/12/2012 18:00 | Winner: Olympiakos Volou | ||||
| 1st(1st leg) | AE Lárissa | - | Asteras Tripolis | 0:0 (0:0) | ||
| 2nd (2nd leg) | Asteras Tripolis | - | AE Lárissa | 4:1 (2:0) | ||
| 1st(1st leg): 12/12/2012 18:30 | 2nd (2nd leg): 22/12/2012 15:00 | Winner: Asteras Tripolis | ||||
| 1st(1st leg) | Platanias Chanion | - | Anagennisi Karditsa | 3:1 (2:1) | ||
| 2nd (2nd leg) | Anagennisi Karditsa | - | Platanias Chanion | 0:1 (0:1) | ||
| 1st(1st leg): 13/12/2012 14:30 | 2nd (2nd leg): 23/12/2012 15:00 | Winner: Platanias Chanion | ||||
| 1st(1st leg) | AO Kavala | - | AEK Athen | 0:0 (0:0) | ||
| 2nd (2nd leg) | AEK Athen | - | AO Kavala | 0:1 (0:0) | ||
| 1st(1st leg): 13/12/2012 16:30 | 2nd (2nd leg): 20/12/2012 18:00 | Winner: AO Kavala | ||||
| 1st(1st leg) | Ethnikos Gazoros | - | Skoda Xanthi | 1:1 (0:0) | ||
| 2nd (2nd leg) | Skoda Xanthi | - | Ethnikos Gazoros | 5:4 (0:1, 1:1, 1:1) pso | ||
| 1st(1st leg): 13/12/2012 18:30 | 2nd (2nd leg): 23/12/2012 15:00 | Winner: Skoda Xanthi | ||||
| 1st(1st leg) | Aiginiakos FC | - | PAOK Saloniki | 1:3 (1:2) | ||
| 2nd (2nd leg) | PAOK Saloniki | - | Aiginiakos FC | 2:1 (1:0) | ||
| 1st(1st leg): 13/12/2012 18:30 | 2nd (2nd leg): 22/12/2012 18:00 | Winner: PAOK Saloniki | ||||
