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| 1st(1st leg) | Sporting Covilhã | - | FC Penafiel | 3:1 (1:0) | ||
| 2nd (2nd leg) | FC Penafiel | - | Sporting Covilhã | 1:0 (1:0) | ||
| 1st(1st leg): 24/09/2014 16:00 | 2nd (2nd leg): 16/11/2014 16:00 | Winner: Sporting Covilhã | ||||
| 1st(1st leg) | União da Madeira | - | Paços de Ferreira | 4:2 (3:1) | ||
| 2nd (2nd leg) | Paços de Ferreira | - | União da Madeira | 2:2 (1:1) | ||
| 1st(1st leg): 24/09/2014 16:00 | 2nd (2nd leg): 29/10/2014 16:00 | Winner: União da Madeira | ||||
| 1st(1st leg) | Oriental de Lisboa | - | Boavista | 0:0 (0:0) | ||
| 2nd (2nd leg) | Boavista | - | Oriental de Lisboa | 5:0 (3:0) | ||
| 1st(1st leg): 24/09/2014 16:00 | 2nd (2nd leg): 16/11/2014 16:00 | Winner: Boavista | ||||
| 1st(1st leg) | Atlético CP | - | Gil Vicente | 0:2 (0:1) | ||
| 2nd (2nd leg) | Gil Vicente | - | Atlético CP | 1:1 (1:1) | ||
| 1st(1st leg): 24/09/2014 16:00 | 2nd (2nd leg): 29/10/2014 16:00 | Winner: Gil Vicente | ||||
| 1st(1st leg) | Académico de Viseu | - | Os Belenenses | 3:1 (1:0) | ||
| 2nd (2nd leg) | Os Belenenses | - | Académico de Viseu | 4:1 (0:0, 2:0) pso | ||
| 1st(1st leg): 24/09/2014 16:00 | 2nd (2nd leg): 29/10/2014 16:00 | Winner: Os Belenenses | ||||
| 1st(1st leg) | CD Tondela | - | FC Arouca | 1:1 (0:0) | ||
| 2nd (2nd leg) | FC Arouca | - | CD Tondela | 1:0 (0:0) | ||
| 1st(1st leg): 24/09/2014 16:00 | 2nd (2nd leg): 29/10/2014 16:00 | Winner: FC Arouca | ||||
| 1st(1st leg) | CD Trofense | - | Moreirense FC | 1:2 (0:1) | ||
| 2nd (2nd leg) | Moreirense FC | - | CD Trofense | 5:4 (1:1, 1:2) pso | ||
| 1st(1st leg): 24/09/2014 18:00 | 2nd (2nd leg): 29/10/2014 16:00 | Winner: Moreirense FC | ||||
| 1st(1st leg) | GD Chaves | - | Rio Ave FC | 1:1 (1:0) | ||
| 2nd (2nd leg) | Rio Ave FC | - | GD Chaves | 4:2 (0:0, 0:0) pso | ||
| 1st(1st leg): 24/09/2014 18:30 | 2nd (2nd leg): 16/11/2014 18:30 | Winner: Rio Ave FC | ||||
