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| 1st(1st leg) | 1. FC Kaiserslautern | - | PSV Eindhoven | 1:0 (1:0) | ||
| 2nd (2nd leg) | PSV Eindhoven | - | 1. FC Kaiserslautern | 0:1 (0:0) | ||
| 1st(1st leg): 08/03/2001 | 2nd (2nd leg): 15/03/2001 | Winner: 1. FC Kaiserslautern | ||||
| 1st(1st leg) | FC Barcelona | - | RC Celta | 2:1 (1:0) | ||
| 2nd (2nd leg) | RC Celta | - | FC Barcelona | 3:2 (1:2) | ||
| 1st(1st leg): 08/03/2001 | 2nd (2nd leg): 15/03/2001 | Winner: FC Barcelona | ||||
| 1st(1st leg) | CD Alavés | - | Rayo Vallecano | 3:0 (1:0) | ||
| 2nd (2nd leg) | Rayo Vallecano | - | CD Alavés | 2:1 (1:1) | ||
| 1st(1st leg): 08/03/2001 | 2nd (2nd leg): 15/03/2001 | Winner: CD Alavés | ||||
| 1st(1st leg) | FC Porto | - | Liverpool FC | 0:0 (0:0) | ||
| 2nd (2nd leg) | Liverpool FC | - | FC Porto | 2:0 (2:0) | ||
| 1st(1st leg): 08/03/2001 | 2nd (2nd leg): 15/03/2001 | Winner: Liverpool FC | ||||
