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| 1st(1st leg) | Levski Sofia | - | FC Schalke 04 | 1:3 (1:0) | ||
| 2nd (2nd leg) | FC Schalke 04 | - | Levski Sofia | 1:1 (0:1) | ||
| 1st(1st leg): 30/03/2006 18:00 | 2nd (2nd leg): 06/04/2006 19:30 | Winner: FC Schalke 04 | ||||
| 1st(1st leg) | Rapid Bucureşti | - | FC Steaua Bucureşti | 1:1 (0:1) | ||
| 2nd (2nd leg) | FC Steaua Bucureşti | - | Rapid Bucureşti | 0:0 (0:0) | ||
| 1st(1st leg): 30/03/2006 18:45 | 2nd (2nd leg): 06/04/2006 18:30 | Winner: FC Steaua Bucureşti | ||||
| 1st(1st leg) | FC Basel | - | Middlesbrough FC | 2:0 (2:0) | ||
| 2nd (2nd leg) | Middlesbrough FC | - | FC Basel | 4:1 (1:1) | ||
| 1st(1st leg): 30/03/2006 19:45 | 2nd (2nd leg): 06/04/2006 20:00 | Winner: Middlesbrough FC | ||||
| 1st(1st leg) | Sevilla FC | - | Zenit St. Petersburg | 4:1 (1:1) | ||
| 2nd (2nd leg) | Zenit St. Petersburg | - | Sevilla FC | 1:1 (0:0) | ||
| 1st(1st leg): 30/03/2006 20:00 | 2nd (2nd leg): 06/04/2006 17:00 | Winner: Sevilla FC | ||||
