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| 22/08/2014 | Stal Alchevsk | - | Stal Dniprodzerzhynsk (old) | 0:3 dec. | ||
| 16:30 | FK Ternopil | - | FK Oleksandriya | 3:4 (1:1, 1:1, 1:1) pso | ||
| 23/08/2014 | 14:00 | MFK Mikolaiv | - | FK Illichivets | 0:1 (0:0) | |
| 14:30 | FK Poltava | - | Metalurh Donetsk | 2:1 (1:1) | ||
| 15:00 | FK Bukovina | - | Chernomorets Odessa | 0:4 (0:3) | ||
| 15:00 | Desna Chernigov | - | Dnipro Dnipropetrovsk | 0:1 (0:1) | ||
| 15:00 | Niva Ternopil | - | Vorskla Poltava | 1:5 (1:2) | ||
| 15:00 | Chaika Petropavlivska Borshchahivka | - | Karpaty Lviv | 0:4 (0:3) | ||
| 15:30 | Real Pharma Ovidiopol | - | Olimpik Donetsk | 0:1 (0:1) | ||
| 16:00 | Naftovik-Ukrnafta | - | Volyn Lutsk | 0:1 (0:1) | ||
| 16:00 | Helios Kharkiv | - | Metalurg Zaporizhya | 0:1 (0:0) | ||
| 16:00 | Zirka Kirovograd | - | Dinamo Kiev | 1:3 (0:2) | ||
| 17:00 | FC Cherkaskyi Dnipro | - | Hoverla Uzhgorod | 1:2 (1:1) | ||
| 17:30 | FK Obolon-Brovar | - | Shakhtar Donetsk | 0:1 (0:0) | ||
| 24/08/2014 | 15:00 | FK Kremin | - | Zorya Lugansk | 0:2 (0:1) | |
| 17:30 | PFC Sumy | - | Metalist Kharkiv | 0:1 (0:0, 0:0) aet |
