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| 1st(1st leg) | FK Poltava | - | Shakhtar Donetsk | 1:5 (1:1) | ||
| 2nd (2nd leg) | Shakhtar Donetsk | - | FK Poltava | 4:1 (4:0) | ||
| 1st(1st leg): 25/09/2014 14:00 | 2nd (2nd leg): 27/10/2014 13:00 | Winner: Shakhtar Donetsk | ||||
| 1st(1st leg) | FK Oleksandriya | - | Zorya Lugansk | 0:1 (0:0) | ||
| 2nd (2nd leg) | Zorya Lugansk | - | FK Oleksandriya | 1:1 (1:1) | ||
| 1st(1st leg): 26/09/2014 16:30 | 2nd (2nd leg): 30/10/2014 15:00 | Winner: Zorya Lugansk | ||||
| 1st(1st leg) | FK Illichivets | - | Vorskla Poltava | 0:1 (0:1) | ||
| 2nd (2nd leg) | Vorskla Poltava | - | FK Illichivets | 3:2 (0:2) | ||
| 1st(1st leg): 27/09/2014 12:00 | 2nd (2nd leg): 29/10/2014 15:00 | Winner: Vorskla Poltava | ||||
| 1st(1st leg) | Hoverla Uzhgorod | - | Metalist Kharkiv | 2:2 (1:0) | ||
| 2nd (2nd leg) | Metalist Kharkiv | - | Hoverla Uzhgorod | 1:1 (1:0) | ||
| 1st(1st leg): 27/09/2014 15:00 | 2nd (2nd leg): 29/10/2014 17:30 | Winner: Metalist Kharkiv | ||||
| 1st(1st leg) | Volyn Lutsk | - | Dnipro Dnipropetrovsk | 1:0 (1:0) | ||
| 2nd (2nd leg) | Dnipro Dnipropetrovsk | - | Volyn Lutsk | 4:0 (1:0) | ||
| 1st(1st leg): 27/09/2014 15:00 | 2nd (2nd leg): 27/10/2014 17:00 | Winner: Dnipro Dnipropetrovsk | ||||
| 1st(1st leg) | Karpaty Lviv | - | Dinamo Kiev | 0:1 (0:1) | ||
| 2nd (2nd leg) | Dinamo Kiev | - | Karpaty Lviv | 1:0 (0:0) | ||
| 1st(1st leg): 27/09/2014 17:30 | 2nd (2nd leg): 28/10/2014 17:00 | Winner: Dinamo Kiev | ||||
| 1st(1st leg) | Stal Dniprodzerzhynsk (old) | - | Chernomorets Odessa | 2:1 (1:1) | ||
| 2nd (2nd leg) | Chernomorets Odessa | - | Stal Dniprodzerzhynsk (old) | 4:2 (1:0, 2:1, 2:1) pso | ||
| 1st(1st leg): 28/09/2014 12:00 | 2nd (2nd leg): 29/10/2014 17:00 | Winner: Chernomorets Odessa | ||||
| 1st(1st leg) | Olimpik Donetsk | - | Metalurg Zaporizhya | 2:0 (1:0) | ||
| 2nd (2nd leg) | Metalurg Zaporizhya | - | Olimpik Donetsk | 0:4 (0:3) | ||
| 1st(1st leg): 28/09/2014 14:00 | 2nd (2nd leg): 28/10/2014 15:00 | Winner: Olimpik Donetsk | ||||
