5. Round | 20/09/2019 | FC Schalke 04 | - | 1. FSV Mainz 05 | 2:1 | ||||
6. Round | 28/09/2019 | 1. FSV Mainz 05 | - | VfL Wolfsburg | 0:1 | ||||
11. Round | 09/11/2019 | 1. FSV Mainz 05 | - | 1. FC Union Berlin | 2:3 | ||||
13. Round | 02/12/2019 | 1. FSV Mainz 05 | - | Eintracht Frankfurt | 2:1 | ||||
15. Round | 14/12/2019 | 1. FSV Mainz 05 | - | Borussia Dortmund | 0:4 |