| 2. Round | 10/09/2003 | Chile | - | Peru | 2:1 | ||||
| 4. Round | 19/11/2003 | Chile | - | Paraguay | 0:1 | ||||
| 6. Round | 02/06/2004 | Venezuela | - | Chile | 0:1 | ||||
| 7. Round | 07/06/2004 | Chile | - | Brazil | 1:1 | ||||
| 8. Round | 06/09/2004 | Chile | - | Colombia | 0:0 | ||||
| 11. Round | 18/11/2004 | Peru | - | Chile | 2:1 | ||||
| 12. Round | 27/03/2005 | Chile | - | Uruguay | 1:1 | ||||
| 13. Round | 31/03/2005 | Paraguay | - | Chile | 2:1 | ||||
| 14. Round | 05/06/2005 | Chile | - | Bolivia | 3:1 | ||||
| 15. Round | 09/06/2005 | Chile | - | Venezuela | 2:1 | ||||
| 16. Round | 04/09/2005 | Brazil | - | Chile | 5:0 | ||||
| 17. Round | 08/10/2005 | Colombia | - | Chile | 1:1 | ||||
| 18. Round | 13/10/2005 | Chile | - | Ecuador | 0:0 |
Chile