| 2. Round | 30/07/2006 | Metalurh Donetsk | - | Stal Alchevsk | 2:1 | ||||
| 3. Round | 05/08/2006 | Stal Alchevsk | - | FK Illichivets | 0:2 | ||||
| 5. Round | 27/08/2006 | Stal Alchevsk | - | Tavriya Simferopol (1958-2014) | 0:1 | ||||
| 6. Round | 10/09/2006 | Dnipro Dnipropetrovsk | - | Stal Alchevsk | 0:0 | ||||
| 7. Round | 16/09/2006 | Stal Alchevsk | - | Arsenal Kiev | 1:1 | ||||
| 8. Round | 24/09/2006 | Stal Alchevsk | - | FK Kharkiv | 4:2 | ||||
| 9. Round | 01/10/2006 | Shakhtar Donetsk | - | Stal Alchevsk | 3:1 | ||||
| 10. Round | 15/10/2006 | Stal Alchevsk | - | Karpaty Lviv | 0:1 |  |
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| 11. Round | 21/10/2006 | Dinamo Kiev | - | Stal Alchevsk | 3:1 | ||||
| 12. Round | 29/10/2006 | Stal Alchevsk | - | Chernomorets Odessa | 2:1 | ||||
| 15. Round | 19/11/2006 | Zorya Lugansk | - | Stal Alchevsk | 1:0 | ||||
| 16. Round | 26/11/2006 | Metalist Kharkiv | - | Stal Alchevsk | 1:0 |
Georgia