| 2. Round | 22/07/2013 | Zorya Lugansk | - | Metalurg Zaporizhya | 0:0 | ||||
| 3. Round | 27/07/2013 | Metalurg Zaporizhya | - | Volyn Lutsk | 3:0 |  |
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| 4. Round | 03/08/2013 | Hoverla Uzhgorod | - | Metalurg Zaporizhya | 1:1 | ||||
| 5. Round | 09/08/2013 | Metalurg Zaporizhya | - | PFK Sevastopol | 2:2 | ||||
| 6. Round | 18/08/2013 | Shakhtar Donetsk | - | Metalurg Zaporizhya | 2:0 |  |
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| 7. Round | 25/08/2013 | Metalurg Zaporizhya | - | Dinamo Kiev | 1:2 | ||||
| 8. Round | 30/08/2013 | Tavriya Simferopol (1958-2014) | - | Metalurg Zaporizhya | 3:1 | ||||
| 10. Round | 22/09/2013 | Metalurg Zaporizhya | - | Dnipro Dnipropetrovsk | 2:3 | ||||
| 11. Round | 29/09/2013 | Metalist Kharkiv | - | Metalurg Zaporizhya | 3:2 | ||||
| 13. Round | 19/10/2013 | Vorskla Poltava | - | Metalurg Zaporizhya | 2:1 | ||||
| 14. Round | 26/10/2013 | Metalurg Zaporizhya | - | Metalurh Donetsk | 0:0 | |
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| 16. Round | 08/11/2013 | FK Illichivets | - | Metalurg Zaporizhya | 3:1 | ||||
| 18. Round | 01/12/2013 | Volyn Lutsk | - | Metalurg Zaporizhya | 2:0 | ||||
| 22. Round | 22/03/2014 | Dinamo Kiev | - | Metalurg Zaporizhya | 4:0 | ||||
| 27. Round | 27/04/2014 | Karpaty Lviv | - | Metalurg Zaporizhya | 2:2 | |
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Ukraine