| 1. Round | 03/08/2013 | Sparta Rotterdam | - | Jong PSV | 2:2 | ||||
| 2. Round | 12/08/2013 | Jong PSV | - | SBV Excelsior | 1:1 | ||||
| 5. Round | 30/08/2013 | FC Dordrecht | - | Jong PSV | 2:0 | ||||
| 6. Round | 02/09/2013 | Jong PSV | - | Jong Ajax | 2:4 | ||||
| 7. Round | 08/09/2013 | Willem II | - | Jong PSV | 2:0 | ||||
| 8. Round | 16/09/2013 | Jong PSV | - | Fortuna Sittard | 0:0 | ||||
| 9. Round | 20/09/2013 | FC Den Bosch | - | Jong PSV | 2:1 | ||||
| 11. Round | 06/10/2013 | Achilles'29 | - | Jong PSV | 3:2 | ||||
| 12. Round | 14/10/2013 | Jong PSV | - | FC Volendam | 3:0 | ||||
| 15. Round | 03/11/2013 | VVV-Venlo | - | Jong PSV | 0:2 | ||||
| 16. Round | 11/11/2013 | Jong PSV | - | MVV | 3:2 | ||||
| 17. Round | 16/11/2013 | FC Emmen | - | Jong PSV | 0:2 | ||||
| 20. Round | 09/12/2013 | Jong Ajax | - | Jong PSV | 2:2 |
Netherlands