| 1. Round | 05/02/2023 | CD Guabirá | - | Bolívar | 1:2 |  |
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| 2. Round | 12/02/2023 | Bolívar | - | Royal Pari | 3:1 | ||||
| 3. Round | 18/02/2023 | The Strongest | - | Bolívar | 3:2 | ||||
| 4. Round | 26/02/2023 | Bolívar | - | Oriente Petrolero | 4:0 | ||||
| 5. Round | 05/03/2023 | Blooming | - | Bolívar | 0:5 | ||||
| 6. Round | 12/03/2023 | Bolívar | - | Club Aurora | 1:0 | ||||
| 8. Round | 09/04/2023 | Bolívar | - | Vaca Díez | 3:0 | ||||
| 9. Round | 15/04/2023 | Always Ready | - | Bolívar | 2:2 | ||||
| 10. Round | 23/04/2023 | Bolívar | - | Jorge Wilstermann | 1:3 | ||||
| 11. Round | 30/04/2023 | Nacional Potosí | - | Bolívar | 3:2 | |
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| 12. Round | 09/05/2023 | Bolívar | - | Universitario de Vinto | 1:1 | ||||
| 13. Round | 14/05/2023 | Independiente Petrolero | - | Bolívar | 2:1 | ||||
| 15. Round | 27/05/2023 | Bolívar | - | Atlético Palmaflor | 5:1 | ||||
| 16. Round | 03/06/2023 | Real Tomayapo | - | Bolívar | 0:0 | ||||
| 17. Round | 25/06/2023 | Bolívar | - | Real Santa Cruz | 3:0 |
Bolivia