| 1. Round | 14/07/2012 | Zorya Lugansk | - | Metalurg Zaporizhya | 2:0 |  |
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| 2. Round | 22/07/2012 | Metalurg Zaporizhya | - | Dnipro Dnipropetrovsk | 0:4 |  |
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| 5. Round | 10/08/2012 | Tavriya Simferopol (1958-2014) | - | Metalurg Zaporizhya | 1:0 | |
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| 6. Round | 19/08/2012 | Karpaty Lviv | - | Metalurg Zaporizhya | 2:1 | |
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| 7. Round | 26/08/2012 | Metalurg Zaporizhya | - | Metalurh Donetsk | 1:2 | ||||
| 9. Round | 16/09/2012 | Metalurg Zaporizhya | - | Hoverla Uzhgorod | 1:1 | ||||
| 10. Round | 30/09/2012 | FK Krivbas (old) | - | Metalurg Zaporizhya | 5:0 | ||||
| 11. Round | 06/10/2012 | Metalurg Zaporizhya | - | Volyn Lutsk | 0:3 | ||||
| 12. Round | 21/10/2012 | Vorskla Poltava | - | Metalurg Zaporizhya | 5:0 | |
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| 17. Round | 26/11/2012 | Dnipro Dnipropetrovsk | - | Metalurg Zaporizhya | 3:0 |
Ukraine