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| 11/02/2025 | 10:00 | Dinamo Kiev | - | Atalanta | 6:7 (3:1, 3:3) pso | |
| 13:00 | VfB Stuttgart | - | Liverpool FC | 5:3 (2:2, 2:2) pso | ||
| 13:00 | AZ Alkmaar | - | SL Benfica | 4:3 (0:1, 2:2) pso | ||
| 15:00 | Inter | - | Lille OSC | 3:1 (2:0) | ||
| 15:00 | Real Betis | - | Bayern München | 0:1 (0:0) | ||
| 17:00 | 1899 Hoffenheim | - | Shakhtar Donetsk | 5:1 (2:0) | ||
| 12/02/2025 | 11:00 | Lokomotiva Zagreb | - | Sturm Graz | 3:5 (0:1, 1:1) pso | |
| 13:00 | Sporting CP | - | AS Monaco | 4:0 (2:0) | ||
| 13:00 | RB Salzburg | - | Celtic FC | 4:2 (0:0, 1:1) pso | ||
| 13:00 | FC Barcelona | - | Dinamo Zagreb | 5:3 (2:2, 2:2) pso | ||
| 13:00 | FC Midtjylland | - | Manchester City | 4:5 (1:0, 2:2) pso | ||
| 15:00 | Real Madrid | - | Borussia Dortmund | 2:0 (1:0) | ||
| 15:00 | Trabzonspor | - | Juventus | 1:0 (0:0) | ||
| 15:00 | Olympiakos Piraeus | - | Girona FC | 1:0 (0:0) | ||
| 15:00 | Puskás FC | - | Aston Villa | 1:2 (0:0) | ||
| 17:30 | Rapid Wien | - | Atlético Madrid | 1:2 (1:1) |
