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| 1st(1st leg) | Jataiense - GO | - | Aparecidense - GO | 0:3 (0:1) | ||
| 2nd (2nd leg) | Aparecidense - GO | - | Jataiense - GO | 2:1 (2:1) | ||
| 1st(1st leg): 25/04/2021 19:30 | 2nd (2nd leg): 01/05/2021 20:00 | Winner: Aparecidense - GO | ||||
| 1st(1st leg) | Iporá - GO | - | Grêmio Anápolis - GO | 0:0 (0:0) | ||
| 2nd (2nd leg) | Grêmio Anápolis - GO | - | Iporá - GO | 2:1 (0:0) | ||
| 1st(1st leg): 25/04/2021 19:30 | 2nd (2nd leg): 01/05/2021 20:00 | Winner: Grêmio Anápolis - GO | ||||
| 1st(1st leg) | Goiás - GO | - | Atlético Goianiense | 0:3 (0:1) | ||
| 2nd (2nd leg) | Atlético Goianiense | - | Goiás - GO | 0:0 (0:0) | ||
| 1st(1st leg): 25/04/2021 20:00 | 2nd (2nd leg): 02/05/2021 20:00 | Winner: Atlético Goianiense | ||||
| 1st(1st leg) | Anápolis FC - GO | - | Vila Nova - GO | 0:3 (0:2) | ||
| 2nd (2nd leg) | Vila Nova - GO | - | Anápolis FC - GO | 3:1 (3:0) | ||
| 1st(1st leg): 25/04/2021 20:00 | 2nd (2nd leg): 30/04/2021 19:30 | Winner: Vila Nova - GO | ||||
