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| 1st(1st leg) | Flamengo RJ | - | Palmeiras | 7:3 (4:0) | ||
| 2nd (2nd leg) | Palmeiras | - | Flamengo RJ | 3:5 (2:3) | ||
| 1st(1st leg): 05/10/2021 19:15 | 2nd (2nd leg): 13/10/2021 21:00 | Winner: Flamengo RJ | ||||
| 1st(1st leg) | Atlético Mineiro | - | São Paulo FC | 0:1 (0:1) | ||
| 2nd (2nd leg) | São Paulo FC | - | Atlético Mineiro | 3:1 (2:1) | ||
| 1st(1st leg): 07/10/2021 20:00 | 2nd (2nd leg): 19/10/2021 20:00 | Winner: São Paulo FC | ||||
