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| 1st(1st leg) | Manchester City | - | FC Barcelona | 0:2 (0:0) | ||
| 2nd (2nd leg) | FC Barcelona | - | Manchester City | 2:1 (0:0) | ||
| 1st(1st leg): 18/02/2014 19:45 | 2nd (2nd leg): 12/03/2014 19:45 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Bayer Leverkusen | - | Paris Saint-Germain | 0:4 (0:3) | ||
| 2nd (2nd leg) | Paris Saint-Germain | - | Bayer Leverkusen | 2:1 (1:1) | ||
| 1st(1st leg): 18/02/2014 19:45 | 2nd (2nd leg): 12/03/2014 19:45 | Winner: Paris Saint-Germain | ||||
| 1st(1st leg) | AC Milan | - | Atlético Madrid | 0:1 (0:0) | ||
| 2nd (2nd leg) | Atlético Madrid | - | AC Milan | 4:1 (2:1) | ||
| 1st(1st leg): 19/02/2014 19:45 | 2nd (2nd leg): 11/03/2014 19:45 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | Arsenal FC | - | Bayern München | 0:2 (0:0) | ||
| 2nd (2nd leg) | Bayern München | - | Arsenal FC | 1:1 (0:0) | ||
| 1st(1st leg): 19/02/2014 19:45 | 2nd (2nd leg): 11/03/2014 19:45 | Winner: Bayern München | ||||
| 1st(1st leg) | Zenit St. Petersburg | - | Borussia Dortmund | 2:4 (0:2) | ||
| 2nd (2nd leg) | Borussia Dortmund | - | Zenit St. Petersburg | 1:2 (1:1) | ||
| 1st(1st leg): 25/02/2014 17:00 | 2nd (2nd leg): 19/03/2014 19:45 | Winner: Borussia Dortmund | ||||
| 1st(1st leg) | Olympiakos Piraeus | - | Manchester United | 2:0 (1:0) | ||
| 2nd (2nd leg) | Manchester United | - | Olympiakos Piraeus | 3:0 (2:0) | ||
| 1st(1st leg): 25/02/2014 19:45 | 2nd (2nd leg): 19/03/2014 19:45 | Winner: Manchester United | ||||
| 1st(1st leg) | Galatasaray | - | Chelsea FC | 1:1 (0:1) | ||
| 2nd (2nd leg) | Chelsea FC | - | Galatasaray | 2:0 (2:0) | ||
| 1st(1st leg): 26/02/2014 19:45 | 2nd (2nd leg): 18/03/2014 19:45 | Winner: Chelsea FC | ||||
| 1st(1st leg) | FC Schalke 04 | - | Real Madrid | 1:6 (0:2) | ||
| 2nd (2nd leg) | Real Madrid | - | FC Schalke 04 | 3:1 (1:1) | ||
| 1st(1st leg): 26/02/2014 19:45 | 2nd (2nd leg): 18/03/2014 19:45 | Winner: Real Madrid | ||||
