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| 1st(1st leg) | Manchester City | - | Real Madrid | 4:3 (2:1) | ||
| 2nd (2nd leg) | Real Madrid | - | Manchester City | 3:1 (0:0, 2:1) aet | ||
| 1st(1st leg): 26/04/2022 20:00 | 2nd (2nd leg): 04/05/2022 20:00 | Winner: Real Madrid | ||||
| 1st(1st leg) | Liverpool FC | - | Villarreal CF | 2:0 (0:0) | ||
| 2nd (2nd leg) | Villarreal CF | - | Liverpool FC | 2:3 (2:0) | ||
| 1st(1st leg): 27/04/2022 20:00 | 2nd (2nd leg): 03/05/2022 20:00 | Winner: Liverpool FC | ||||
