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| 1st(1st leg) | Quilmes | - | Colo-Colo | 0:0 (0:0) | ||
| 2nd (2nd leg) | Colo-Colo | - | Quilmes | 2:2 (2:1) | ||
| 1st(1st leg): 01/02/2005 23:00 | 2nd (2nd leg): 08/02/2005 23:30 | Winner: Quilmes | ||||
| 1st(1st leg) | Mineros de Guayana | - | América de Cali | 0:2 (0:2) | ||
| 2nd (2nd leg) | América de Cali | - | Mineros de Guayana | 3:1 (2:1) | ||
| 1st(1st leg): 02/02/2005 01:30 | 2nd (2nd leg): 09/02/2005 01:00 | Winner: América de Cali | ||||
| 1st(1st leg) | Tacuary | - | Palmeiras | 2:2 (1:1) | ||
| 2nd (2nd leg) | Palmeiras | - | Tacuary | 2:0 (1:0) | ||
| 1st(1st leg): 02/02/2005 21:30 | 2nd (2nd leg): 09/02/2005 23:30 | Winner: Palmeiras | ||||
| 1st(1st leg) | Deportivo Guadalajara | - | Cienciano | 3:1 (1:1) | ||
| 2nd (2nd leg) | Cienciano | - | Deportivo Guadalajara | 1:5 (0:0) | ||
| 1st(1st leg): 03/02/2005 00:30 | 2nd (2nd leg): 10/02/2005 00:00 | Winner: Deportivo Guadalajara | ||||
| 1st(1st leg) | Atlético Junior | - | Oriente Petrolero | 2:1 (2:0) | ||
| 2nd (2nd leg) | Oriente Petrolero | - | Atlético Junior | 1:3 (1:2) | ||
| 1st(1st leg): 03/02/2005 21:00 | 2nd (2nd leg): 10/02/2005 22:00 | Winner: Atlético Junior | ||||
| 1st(1st leg) | LDU Quito | - | Peñarol | 3:0 (0:0) | ||
| 2nd (2nd leg) | Peñarol | - | LDU Quito | 4:1 (2:1) | ||
| 1st(1st leg): 03/02/2005 23:30 | 2nd (2nd leg): 10/02/2005 19:30 | Winner: LDU Quito | ||||
