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| 1st(1st leg) | Estudiantes | - | Goiás - GO | 2:0 (0:0) | ||
| 2nd (2nd leg) | Goiás - GO | - | Estudiantes | 3:1 (0:0) | ||
| 1st(1st leg): 25/04/2006 23:15 | 2nd (2nd leg): 04/05/2006 23:15 | Winner: Estudiantes | ||||
| 1st(1st leg) | LDU Quito | - | Atlético Nacional | 4:0 (2:0) | ||
| 2nd (2nd leg) | Atlético Nacional | - | LDU Quito | 0:1 (0:1) | ||
| 1st(1st leg): 26/04/2006 02:30 | 2nd (2nd leg): 03/05/2006 00:15 | Winner: LDU Quito | ||||
| 1st(1st leg) | Palmeiras | - | São Paulo FC | 1:1 (1:1) | ||
| 2nd (2nd leg) | São Paulo FC | - | Palmeiras | 2:1 (1:0) | ||
| 1st(1st leg): 26/04/2006 23:15 | 2nd (2nd leg): 04/05/2006 01:45 | Winner: São Paulo FC | ||||
| 1st(1st leg) | River Plate | - | Corinthians SP | 3:2 (2:1) | ||
| 2nd (2nd leg) | Corinthians SP | - | River Plate | 1:3 (1:0) | ||
| 1st(1st leg): 27/04/2006 01:45 | 2nd (2nd leg): 05/05/2006 01:45 | Winner: River Plate | ||||
| 1st(1st leg) | Deportivo Guadalajara | - | Santa Fe | 3:0 (1:0) | ||
| 2nd (2nd leg) | Santa Fe | - | Deportivo Guadalajara | 3:1 (1:1) | ||
| 1st(1st leg): 27/04/2006 03:50 | 2nd (2nd leg): 03/05/2006 02:45 | Winner: Deportivo Guadalajara | ||||
| 1st(1st leg) | Nacional | - | Internacional | 1:2 (1:1) | ||
| 2nd (2nd leg) | Internacional | - | Nacional | 0:0 (0:0) | ||
| 1st(1st leg): 27/04/2006 23:00 | 2nd (2nd leg): 04/05/2006 01:45 | Winner: Internacional | ||||
| 1st(1st leg) | Newell's Old Boys | - | Vélez Sarsfield | 2:4 (1:1) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | Newell's Old Boys | 2:2 (0:0) | ||
| 1st(1st leg): 28/04/2006 01:15 | 2nd (2nd leg): 03/05/2006 23:15 | Winner: Vélez Sarsfield | ||||
| 1st(1st leg) | UANL Tigres | - | Libertad | 0:0 (0:0) | ||
| 2nd (2nd leg) | Libertad | - | UANL Tigres | 5:3 (0:0, 0:0, 0:0) pso | ||
| 1st(1st leg): 28/04/2006 03:30 | 2nd (2nd leg): 04/05/2006 23:15 | Winner: Libertad | ||||
