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| 1st(1st leg) | Deportivo Guadalajara | - | Vélez Sarsfield | 0:0 (0:0) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | Deportivo Guadalajara | 1:2 (0:1) | ||
| 1st(1st leg): 10/05/2006 02:15 | 2nd (2nd leg): 21/07/2006 01:45 | Winner: Deportivo Guadalajara | ||||
| 1st(1st leg) | LDU Quito | - | Internacional | 2:1 (0:1) | ||
| 2nd (2nd leg) | Internacional | - | LDU Quito | 2:0 (0:0) | ||
| 1st(1st leg): 10/05/2006 23:30 | 2nd (2nd leg): 19/07/2006 23:15 | Winner: Internacional | ||||
| 1st(1st leg) | Estudiantes | - | São Paulo FC | 1:0 (0:0) | ||
| 2nd (2nd leg) | São Paulo FC | - | Estudiantes | 4:3 (1:0, 1:0, 1:0) pso | ||
| 1st(1st leg): 11/05/2006 01:45 | 2nd (2nd leg): 20/07/2006 01:45 | Winner: São Paulo FC | ||||
| 1st(1st leg) | River Plate | - | Libertad | 2:2 (0:1) | ||
| 2nd (2nd leg) | Libertad | - | River Plate | 3:1 (2:0) | ||
| 1st(1st leg): 12/05/2006 01:15 | 2nd (2nd leg): 19/07/2006 01:15 | Winner: Libertad | ||||
