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| 1st(1st leg) | Oriente Petrolero | - | Nacional | 1:0 (1:0) | ||
| 2nd (2nd leg) | Nacional | - | Oriente Petrolero | 2:0 (1:0) | ||
| 1st(1st leg): 28/01/2014 23:00 | 2nd (2nd leg): 04/02/2014 23:00 | Winner: Nacional | ||||
| 1st(1st leg) | Monarcas Morelia | - | Santa Fe | 2:1 (1:0) | ||
| 2nd (2nd leg) | Santa Fe | - | Monarcas Morelia | 1:0 (0:0) | ||
| 1st(1st leg): 29/01/2014 01:15 | 2nd (2nd leg): 05/02/2014 01:30 | Winner: Santa Fe | ||||
| 1st(1st leg) | Sporting Cristal | - | Athletico Paranaense | 2:1 (1:0) | ||
| 2nd (2nd leg) | Athletico Paranaense | - | Sporting Cristal | 5:4 (0:0, 2:1, 2:1) pso | ||
| 1st(1st leg): 30/01/2014 00:00 | 2nd (2nd leg): 06/02/2014 00:00 | Winner: Athletico Paranaense | ||||
| 1st(1st leg) | Deportivo Quito | - | Botafogo - RJ | 1:0 (1:0) | ||
| 2nd (2nd leg) | Botafogo - RJ | - | Deportivo Quito | 4:0 (1:0) | ||
| 1st(1st leg): 30/01/2014 00:00 | 2nd (2nd leg): 06/02/2014 00:00 | Winner: Botafogo - RJ | ||||
| 1st(1st leg) | Universidad de Chile | - | Guaraní | 1:0 (0:0) | ||
| 2nd (2nd leg) | Guaraní | - | Universidad de Chile | 2:3 (1:0) | ||
| 1st(1st leg): 30/01/2014 23:00 | 2nd (2nd leg): 06/02/2014 22:30 | Winner: Universidad de Chile | ||||
| 1st(1st leg) | Caracas FC | - | Lanús | 0:2 (0:1) | ||
| 2nd (2nd leg) | Lanús | - | Caracas FC | 1:0 (0:0) | ||
| 1st(1st leg): 31/01/2014 01:15 | 2nd (2nd leg): 07/02/2014 01:00 | Winner: Lanús | ||||
