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| 1st(1st leg) | Grêmio Porto Alegre | - | Palmeiras | 0:1 (0:1) | ||
| 2nd (2nd leg) | Palmeiras | - | Grêmio Porto Alegre | 1:2 (1:2) | ||
| 1st(1st leg): 21/08/2019 01:30 | 2nd (2nd leg): 28/08/2019 01:30 | Winner: Grêmio Porto Alegre | ||||
| 1st(1st leg) | LDU Quito | - | Boca Juniors | 0:3 (0:1) | ||
| 2nd (2nd leg) | Boca Juniors | - | LDU Quito | 0:0 (0:0) | ||
| 1st(1st leg): 21/08/2019 23:15 | 2nd (2nd leg): 28/08/2019 23:15 | Winner: Boca Juniors | ||||
| 1st(1st leg) | Flamengo RJ | - | Internacional | 2:0 (0:0) | ||
| 2nd (2nd leg) | Internacional | - | Flamengo RJ | 1:1 (0:0) | ||
| 1st(1st leg): 22/08/2019 01:30 | 2nd (2nd leg): 29/08/2019 01:30 | Winner: Flamengo RJ | ||||
| 1st(1st leg) | River Plate | - | Cerro Porteño | 2:0 (1:0) | ||
| 2nd (2nd leg) | Cerro Porteño | - | River Plate | 1:1 (1:0) | ||
| 1st(1st leg): 22/08/2019 23:15 | 2nd (2nd leg): 29/08/2019 23:15 | Winner: River Plate | ||||
