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| 1st(1st leg) | Flamengo RJ | - | River Plate | 1:2 (0:0) | ||
| 2nd (2nd leg) | River Plate | - | Flamengo RJ | 4:3 (0:0) | ||
| 1st(1st leg): 31/10/2000 | 2nd (2nd leg): 08/11/2000 | Winner: River Plate | ||||
| 1st(1st leg) | Vasco da Gama - RJ | - | Rosario Central | 1:0 (1:0) | ||
| 2nd (2nd leg) | Rosario Central | - | Vasco da Gama - RJ | 4:5 (0:0, 1:0) pso | ||
| 1st(1st leg): 31/10/2000 | 2nd (2nd leg): 08/11/2000 | Winner: Vasco da Gama - RJ | ||||
| 1st(1st leg) | Palmeiras | - | Cruzeiro | 3:2 (2:0) | ||
| 2nd (2nd leg) | Cruzeiro | - | Palmeiras | 1:2 (0:1) | ||
| 1st(1st leg): 31/10/2000 | 2nd (2nd leg): 08/11/2000 | Winner: Palmeiras | ||||
| 1st(1st leg) | Boca Juniors | - | Atlético Mineiro | 0:2 (0:1) | ||
| 2nd (2nd leg) | Atlético Mineiro | - | Boca Juniors | 2:2 (1:2) | ||
| 1st(1st leg): 01/11/2000 | 2nd (2nd leg): 07/11/2000 | Winner: Atlético Mineiro | ||||
