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| 1st(1st leg) | Universitario de Sucre | - | Deportes Iquique | 2:0 (1:0) | ||
| 2nd (2nd leg) | Deportes Iquique | - | Universitario de Sucre | 1:0 (0:0) | ||
| 1st(1st leg): 19/08/2014 22:00 | 2nd (2nd leg): 27/08/2014 02:00 | Winner: Universitario de Sucre | ||||
| 1st(1st leg) | Rentistas | - | Cerro Porteño | 0:2 (0:1) | ||
| 2nd (2nd leg) | Cerro Porteño | - | Rentistas | 0:1 (0:1) | ||
| 1st(1st leg): 19/08/2014 22:00 | 2nd (2nd leg): 27/08/2014 02:00 | Winner: Cerro Porteño | ||||
| 1st(1st leg) | Águilas Pereira | - | Emelec | 1:1 (0:1) | ||
| 2nd (2nd leg) | Emelec | - | Águilas Pereira | 2:1 (1:0) | ||
| 1st(1st leg): 20/08/2014 00:15 | 2nd (2nd leg): 26/08/2014 23:30 | Winner: Emelec | ||||
| 1st(1st leg) | Universidad Catolica | - | Deportivo Anzoátegui | 1:1 (1:0) | ||
| 2nd (2nd leg) | Deportivo Anzoátegui | - | Universidad Catolica | 4:5 (1:0, 1:1) pso | ||
| 1st(1st leg): 20/08/2014 00:15 | 2nd (2nd leg): 26/08/2014 23:30 | Winner: Universidad Catolica | ||||
| 1st(1st leg) | Huachipato | - | San José | 3:1 (1:0) | ||
| 2nd (2nd leg) | San José | - | Huachipato | 2:3 (0:2) | ||
| 1st(1st leg): 20/08/2014 02:30 | 2nd (2nd leg): 26/08/2014 21:00 | Winner: Huachipato | ||||
| 1st(1st leg) | Nacional Potosí | - | Libertad | 1:0 (1:0) | ||
| 2nd (2nd leg) | Libertad | - | Nacional Potosí | 3:0 (2:0) | ||
| 1st(1st leg): 20/08/2014 22:00 | 2nd (2nd leg): 28/08/2014 00:30 | Winner: Libertad | ||||
| 1st(1st leg) | Universidad Técnica | - | Deportivo Cali | 0:0 (0:0) | ||
| 2nd (2nd leg) | Deportivo Cali | - | Universidad Técnica | 3:0 (2:0) | ||
| 1st(1st leg): 20/08/2014 22:00 | 2nd (2nd leg): 29/08/2014 02:00 | Winner: Deportivo Cali | ||||
| 1st(1st leg) | General Díaz | - | Cobresal | 2:1 (1:1) | ||
| 2nd (2nd leg) | Cobresal | - | General Díaz | 2:2 (1:2) | ||
| 1st(1st leg): 21/08/2014 00:15 | 2nd (2nd leg): 27/08/2014 22:00 | Winner: General Díaz | ||||
| 1st(1st leg) | Peñarol | - | Jorge Wilstermann | 2:0 (1:0) | ||
| 2nd (2nd leg) | Jorge Wilstermann | - | Peñarol | 0:4 (0:1) | ||
| 1st(1st leg): 21/08/2014 00:15 | 2nd (2nd leg): 29/08/2014 02:00 | Winner: Peñarol | ||||
| 1st(1st leg) | Deportivo La Guaira | - | Atlético Nacional | 1:1 (0:0) | ||
| 2nd (2nd leg) | Atlético Nacional | - | Deportivo La Guaira | 1:0 (0:0) | ||
| 1st(1st leg): 21/08/2014 02:30 | 2nd (2nd leg): 28/08/2014 03:00 | Winner: Atlético Nacional | ||||
| 1st(1st leg) | Inti Gas | - | Caracas FC | 0:1 (0:0) | ||
| 2nd (2nd leg) | Caracas FC | - | Inti Gas | 1:0 (1:0) | ||
| 1st(1st leg): 21/08/2014 19:00 | 2nd (2nd leg): 28/08/2014 23:30 | Winner: Caracas FC | ||||
| 1st(1st leg) | Deportivo Capiatá | - | Danubio | 3:1 (1:0) | ||
| 2nd (2nd leg) | Danubio | - | Deportivo Capiatá | 2:2 (1:0) | ||
| 1st(1st leg): 21/08/2014 21:15 | 2nd (2nd leg): 28/08/2014 21:00 | Winner: Deportivo Capiatá | ||||
| 1st(1st leg) | Barcelona | - | Alianza Lima | 3:0 (1:0) | ||
| 2nd (2nd leg) | Alianza Lima | - | Barcelona | 0:0 (0:0) | ||
| 1st(1st leg): 21/08/2014 23:30 | 2nd (2nd leg): 28/08/2014 03:00 | Winner: Barcelona | ||||
| 1st(1st leg) | Trujillanos FC | - | Independiente del Valle | 0:1 (0:0) | ||
| 2nd (2nd leg) | Independiente del Valle | - | Trujillanos FC | 1:1 (0:0) | ||
| 1st(1st leg): 21/08/2014 23:30 | 2nd (2nd leg): 27/08/2014 22:00 | Winner: Independiente del Valle | ||||
| 1st(1st leg) | Universidad Católica | - | River Plate | 0:1 (0:0) | ||
| 2nd (2nd leg) | River Plate | - | Universidad Católica | 3:0 (0:0) | ||
| 1st(1st leg): 22/08/2014 01:50 | 2nd (2nd leg): 28/08/2014 00:30 | Winner: River Plate | ||||
| 1st(1st leg) | Millonarios | - | Universidad Cesar Vallejo | 1:2 (1:2) | ||
| 2nd (2nd leg) | Universidad Cesar Vallejo | - | Millonarios | 2:2 (2:1) | ||
| 1st(1st leg): 22/08/2014 01:50 | 2nd (2nd leg): 28/08/2014 23:30 | Winner: Universidad Cesar Vallejo | ||||
