1st(1st leg) Internacional - Bahia - BA 0:2 (0:1)
2nd (2nd leg) Bahia - BA - Internacional 1:1 (0:1)
1st(1st leg): 28/08/2014 02:00 2nd (2nd leg): 05/09/2014 02:00 Winner: Bahia - BA
1st(1st leg) Fluminense RJ - Goiás - GO 2:1 (2:0)
2nd (2nd leg) Goiás - GO - Fluminense RJ 1:0 (0:0)
1st(1st leg): 28/08/2014 22:00 2nd (2nd leg): 04/09/2014 02:00 Winner: Goiás - GO
1st(1st leg) Criciúma - SC - São Paulo FC 2:1 (2:1)
2nd (2nd leg) São Paulo FC - Criciúma - SC 2:0 (2:0)
1st(1st leg): 29/08/2014 00:00 2nd (2nd leg): 05/09/2014 00:00 Winner: São Paulo FC
1st(1st leg) Sport Recife - PE - Vitória - BA 0:1 (0:1)
2nd (2nd leg) Vitória - BA - Sport Recife - PE 2:1 (1:0)
1st(1st leg): 29/08/2014 02:00 2nd (2nd leg): 04/09/2014 02:00 Winner: Vitória - BA
1st(1st leg) Gimnasia de La Plata - Estudiantes 0:0 (0:0)
2nd (2nd leg) Estudiantes - Gimnasia de La Plata 1:0 (0:0)
1st(1st leg): 03/09/2014 18:00 2nd (2nd leg): 16/09/2014 23:00 Winner: Estudiantes
1st(1st leg) Godoy Cruz - River Plate 0:1 (0:0)
2nd (2nd leg) River Plate - Godoy Cruz 2:0 (2:0)
1st(1st leg): 04/09/2014 01:15 2nd (2nd leg): 18/09/2014 01:15 Winner: River Plate
1st(1st leg) Rosario Central - Boca Juniors 1:1 (0:1)
2nd (2nd leg) Boca Juniors - Rosario Central 3:0 (1:0)
1st(1st leg): 05/09/2014 01:15 2nd (2nd leg): 19/09/2014 01:15 Winner: Boca Juniors
1st(1st leg) Atlético Nacional - General Díaz 0:2 (0:2)
2nd (2nd leg) General Díaz - Atlético Nacional 1:3 (0:1)
1st(1st leg): 11/09/2014 01:15 2nd (2nd leg): 26/09/2014 01:30 Winner: Atlético Nacional
1st(1st leg) Barcelona - Libertad 1:0 (1:0)
2nd (2nd leg) Libertad - Barcelona 2:0 (2:0)
1st(1st leg): 12/09/2014 01:15 2nd (2nd leg): 18/09/2014 01:15 Winner: Libertad
1st(1st leg) Independiente del Valle - Cerro Porteño 1:0 (0:0)
2nd (2nd leg) Cerro Porteño - Independiente del Valle 3:0 (1:0)
1st(1st leg): 16/09/2014 23:00 2nd (2nd leg): 24/09/2014 01:15 Winner: Cerro Porteño
1st(1st leg) Deportivo Capiatá - Caracas FC 1:1 (1:0)
2nd (2nd leg) Caracas FC - Deportivo Capiatá 1:3 (0:1)
1st(1st leg): 17/09/2014 01:15 2nd (2nd leg): 24/09/2014 23:00 Winner: Deportivo Capiatá
1st(1st leg) Peñarol - Deportivo Cali 2:2 (0:0)
2nd (2nd leg) Deportivo Cali - Peñarol 0:1 (0:1)
1st(1st leg): 17/09/2014 01:30 2nd (2nd leg): 25/09/2014 01:15 Winner: Peñarol
1st(1st leg) Huachipato - Universidad Catolica 2:0 (1:0)
2nd (2nd leg) Universidad Catolica - Huachipato 1:0 (1:0)
1st(1st leg): 17/09/2014 22:00 2nd (2nd leg): 24/09/2014 23:00 Winner: Huachipato
1st(1st leg) Universitario de Sucre - Universidad Cesar Vallejo 2:2 (0:0)
2nd (2nd leg) Universidad Cesar Vallejo - Universitario de Sucre 3:0 (0:0)
1st(1st leg): 17/09/2014 23:00 2nd (2nd leg): 23/09/2014 23:00 Winner: Universidad Cesar Vallejo
1st(1st leg) Emelec - River Plate 2:1 (1:0)
2nd (2nd leg) River Plate - Emelec 1:1 (1:1)
1st(1st leg): 19/09/2014 01:15 2nd (2nd leg): 26/09/2014 01:15 Winner: Emelec