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| 1st(1st leg) | Barcelona | - | Delfín SC | 4:1 (1:1) | ||
| 2nd (2nd leg) | Delfín SC | - | Barcelona | 3:0 (1:0) | ||
| 1st(1st leg): 03/10/2019 01:30 | 2nd (2nd leg): 30/10/2019 21:00 | Winner: Delfín SC | ||||
| 1st(1st leg) | LDU Quito | - | Emelec | 2:0 (0:0) | ||
| 2nd (2nd leg) | Emelec | - | LDU Quito | 4:5 (0:0, 2:0, 2:0) pso | ||
| 1st(1st leg): 24/10/2019 01:15 | 2nd (2nd leg): 31/10/2019 00:30 | Winner: LDU Quito | ||||
