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| 1st(1st leg) | Independiente Juniors | - | Delfín SC | 2:3 (1:0) | ||
| 2nd (2nd leg) | Delfín SC | - | Independiente Juniors | 1:0 (0:0) | ||
| 1st(1st leg): 14/08/2019 21:30 | 2nd (2nd leg): 24/09/2019 21:30 | Winner: Delfín SC | ||||
| 1st(1st leg) | El Nacional | - | Barcelona | 1:1 (0:0) | ||
| 2nd (2nd leg) | Barcelona | - | El Nacional | 0:0 (0:0) | ||
| 1st(1st leg): 22/08/2019 01:30 | 2nd (2nd leg): 26/09/2019 01:30 | Winner: Barcelona | ||||
| 1st(1st leg) | Técnico Universitario | - | Emelec | 1:0 (0:0) | ||
| 2nd (2nd leg) | Emelec | - | Técnico Universitario | 2:0 (0:0) | ||
| 1st(1st leg): 29/08/2019 01:30 | 2nd (2nd leg): 25/09/2019 01:30 | Winner: Emelec | ||||
| 1st(1st leg) | Aucas | - | LDU Quito | 0:0 (0:0) | ||
| 2nd (2nd leg) | LDU Quito | - | Aucas | 4:2 (0:0, 0:0, 0:0) pso | ||
| 1st(1st leg): 08/09/2019 18:00 | 2nd (2nd leg): 19/09/2019 01:15 | Winner: LDU Quito | ||||
