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| 1st(1st leg) | Valencia CF | - | Espanyol Barcelona | 5:2 | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | Valencia CF | 1:1 | ||
| 1st(1st leg): 11/05/1986 | 2nd (2nd leg): 18/05/1986 | Winner: Valencia CF | ||||
| 1st(1st leg) | Atlético Madrid | - | Real Valladolid | 3:3 | ||
| 2nd (2nd leg) | Real Valladolid | - | Atlético Madrid | 0:1 | ||
| 1st(1st leg): 11/05/1986 | 2nd (2nd leg): 18/05/1986 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | FC Barcelona | - | Real Madrid | 2:2 | ||
| 2nd (2nd leg) | Real Madrid | - | FC Barcelona | 0:4 | ||
| 1st(1st leg): 11/05/1986 | 2nd (2nd leg): 18/05/1986 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Real Oviedo | - | Real Sociedad | 2:1 | ||
| 2nd (2nd leg) | Real Sociedad | - | Real Oviedo | 4:0 | ||
| 1st(1st leg): 14/05/1986 | 2nd (2nd leg): 21/05/1986 | Winner: Real Sociedad | ||||
| 1st(1st leg) | Sevilla FC | - | Sestao SC | 0:0 | ||
| 2nd (2nd leg) | Sestao SC | - | Sevilla FC | 1:0 | ||
| 1st(1st leg): 14/05/1986 | 2nd (2nd leg): 21/05/1986 | Winner: Sestao SC | ||||
