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| 1st(1st leg) | Athletic Bilbao | - | FC Barcelona | 0:1 (0:1) | ||
| 2nd (2nd leg) | FC Barcelona | - | Athletic Bilbao | 1:0 (0:0) | ||
| 1st(1st leg): 08/11/1989 | 2nd (2nd leg): 29/11/1989 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Atlético Madrid | - | Real Madrid | 0:0 (0:0) | ||
| 2nd (2nd leg) | Real Madrid | - | Atlético Madrid | 2:0 (1:0) | ||
| 1st(1st leg): 08/11/1989 | 2nd (2nd leg): 30/11/1989 | Winner: Real Madrid | ||||
| 1st(1st leg) | Real Betis | - | Cádiz CF | 1:0 (0:0) | ||
| 2nd (2nd leg) | Cádiz CF | - | Real Betis | 2:0 (0:0) | ||
| 1st(1st leg): 08/11/1989 | 2nd (2nd leg): 29/11/1989 | Winner: Cádiz CF | ||||
| 1st(1st leg) | Real Oviedo | - | Real Zaragoza | 0:1 (0:1) | ||
| 2nd (2nd leg) | Real Zaragoza | - | Real Oviedo | 1:1 (1:0) | ||
| 1st(1st leg): 08/11/1989 | 2nd (2nd leg): 29/11/1989 | Winner: Real Zaragoza | ||||
| 1st(1st leg) | CE Sabadell | - | Real Sociedad | 1:0 (0:0) | ||
| 2nd (2nd leg) | Real Sociedad | - | CE Sabadell | 6:5 (1:0, 2:1, 3:2) pso | ||
| 1st(1st leg): 08/11/1989 | 2nd (2nd leg): 29/11/1989 | Winner: Real Sociedad | ||||
| 1st(1st leg) | CD Tenerife | - | Sporting Gijón | 0:0 (0:0) | ||
| 2nd (2nd leg) | Sporting Gijón | - | CD Tenerife | 3:0 (0:0) | ||
| 1st(1st leg): 08/11/1989 | 2nd (2nd leg): 29/11/1989 | Winner: Sporting Gijón | ||||
| 1st(1st leg) | Real Valladolid | - | CD Málaga | 6:1 (3:0) | ||
| 2nd (2nd leg) | CD Málaga | - | Real Valladolid | 2:3 (0:1) | ||
| 1st(1st leg): 08/11/1989 | 2nd (2nd leg): 20/12/1989 | Winner: Real Valladolid | ||||
| 1st(1st leg) | Valencia CF | - | RC Celta | 5:0 (0:0) | ||
| 2nd (2nd leg) | RC Celta | - | Valencia CF | 0:0 (0:0) | ||
| 1st(1st leg): 22/11/1989 | 2nd (2nd leg): 06/12/1989 | Winner: Valencia CF | ||||
