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| 1st(1st leg) | CF Extremadura | - | Real Valladolid | 0:3 (0:1) | ||
| 2nd (2nd leg) | Real Valladolid | - | CF Extremadura | 2:1 (1:1) | ||
| 1st(1st leg): 03/01/1995 | 2nd (2nd leg): 10/01/1995 | Winner: Real Valladolid | ||||
| 1st(1st leg) | CP Mérida | - | Real Sociedad | 1:2 (1:0) | ||
| 2nd (2nd leg) | Real Sociedad | - | CP Mérida | 3:2 (0:1) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Real Sociedad | ||||
| 1st(1st leg) | Sestao SC | - | Getafe CF | 0:0 | ||
| 2nd (2nd leg) | Getafe CF | - | Sestao SC | 0:1 | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Sestao SC | ||||
| 1st(1st leg) | Gimnàstic de Tarragona | - | Real Betis | 1:3 (1:1) | ||
| 2nd (2nd leg) | Real Betis | - | Gimnàstic de Tarragona | 3:0 (3:0) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Real Betis | ||||
| 1st(1st leg) | CD Lugo | - | RC Celta | 2:1 (0:0) | ||
| 2nd (2nd leg) | RC Celta | - | CD Lugo | 5:0 (2:0) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: RC Celta | ||||
| 1st(1st leg) | CD Corralejo | - | Valencia CF | 2:2 (2:1) | ||
| 2nd (2nd leg) | Valencia CF | - | CD Corralejo | 5:0 (1:0) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Valencia CF | ||||
| 1st(1st leg) | Real Jaén | - | Villarreal CF | 0:3 (0:2) | ||
| 2nd (2nd leg) | Villarreal CF | - | Real Jaén | 1:1 (0:0) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Villarreal CF | ||||
| 1st(1st leg) | CD Badajoz | - | CD Logroñés | 1:0 (1:0) | ||
| 2nd (2nd leg) | CD Logroñés | - | CD Badajoz | 0:2 (0:1) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: CD Badajoz | ||||
| 1st(1st leg) | Ontinyent CF | - | RCD Mallorca | 2:2 | ||
| 2nd (2nd leg) | RCD Mallorca | - | Ontinyent CF | 7:3 | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: RCD Mallorca | ||||
| 1st(1st leg) | CD Mensajero | - | Atlético Madrid | 0:0 (0:0) | ||
| 2nd (2nd leg) | Atlético Madrid | - | CD Mensajero | 3:1 (1:0) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 10/01/1995 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | UD Las Palmas | - | CD Tenerife | 0:0 (0:0) | ||
| 2nd (2nd leg) | CD Tenerife | - | UD Las Palmas | 3:4 (0:0, 0:0, 0:0) pso | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 12/01/1995 | Winner: UD Las Palmas | ||||
| 1st(1st leg) | SD Eibar | - | Sporting Gijón | 0:1 (0:0) | ||
| 2nd (2nd leg) | Sporting Gijón | - | SD Eibar | 3:2 (1:1) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Sporting Gijón | ||||
| 1st(1st leg) | UD Salamanca | - | CA Osasuna | 3:1 (1:1) | ||
| 2nd (2nd leg) | CA Osasuna | - | UD Salamanca | 0:2 (0:0) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: UD Salamanca | ||||
| 1st(1st leg) | Palamós CF | - | Espanyol Barcelona | 1:1 (1:0) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | Palamós CF | 3:4 (1:2) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Palamós CF | ||||
| 1st(1st leg) | SD Beasain | - | Albacete | 3:2 (0:2) | ||
| 2nd (2nd leg) | Albacete | - | SD Beasain | 1:0 (0:0) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Albacete | ||||
| 1st(1st leg) | UD SS Reyes | - | Racing Santander | 0:1 (0:1) | ||
| 2nd (2nd leg) | Racing Santander | - | UD SS Reyes | 2:1 (2:0) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Racing Santander | ||||
| 1st(1st leg) | CD Leonesa | - | Sevilla FC | 2:4 (1:2) | ||
| 2nd (2nd leg) | Sevilla FC | - | CD Leonesa | 2:1 (2:0) | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: Sevilla FC | ||||
| 1st(1st leg) | Real Murcia | - | CD Toledo | 0:1 | ||
| 2nd (2nd leg) | CD Toledo | - | Real Murcia | 1:1 | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: CD Toledo | ||||
| 1st(1st leg) | Cartagena FC | - | UE Lleida | 1:0 | ||
| 2nd (2nd leg) | UE Lleida | - | Cartagena FC | 5:0 | ||
| 1st(1st leg): 04/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: UE Lleida | ||||
| 1st(1st leg) | Real Oviedo | - | SD Compostela | 1:2 (1:1) | ||
| 2nd (2nd leg) | SD Compostela | - | Real Oviedo | 1:0 (1:0) | ||
| 1st(1st leg): 05/01/1995 | 2nd (2nd leg): 11/01/1995 | Winner: SD Compostela | ||||
| 1st(1st leg) | FC Andorra | - | Rayo Vallecano | 1:1 | ||
| 2nd (2nd leg) | Rayo Vallecano | - | FC Andorra | 0:0 | ||
| 1st(1st leg): 11/01/1995 | 2nd (2nd leg): 19/01/1995 | Winner: Rayo Vallecano | ||||
