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| 1st(1st leg) | FC Barcelona | - | Atlético Madrid | 1:4 (1:1) | ||
| 2nd (2nd leg) | Atlético Madrid | - | FC Barcelona | 1:3 (1:1) | ||
| 1st(1st leg): 07/02/1995 20:30 | 2nd (2nd leg): 14/02/1995 20:30 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | Athletic Bilbao | - | Real Betis | 4:0 (3:0) | ||
| 2nd (2nd leg) | Real Betis | - | Athletic Bilbao | 1:0 (0:0) | ||
| 1st(1st leg): 08/02/1995 19:15 | 2nd (2nd leg): 15/02/1995 20:15 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | Sporting Gijón | - | CD Badajoz | 1:1 (1:1) | ||
| 2nd (2nd leg) | CD Badajoz | - | Sporting Gijón | 0:3 (0:0) | ||
| 1st(1st leg): 08/02/1995 19:30 | 2nd (2nd leg): 15/02/1995 20:00 | Winner: Sporting Gijón | ||||
| 1st(1st leg) | Palamós CF | - | Rayo Vallecano | 0:1 (0:1) | ||
| 2nd (2nd leg) | Rayo Vallecano | - | Palamós CF | 1:1 (1:0) | ||
| 1st(1st leg): 08/02/1995 19:45 | 2nd (2nd leg): 15/02/1995 20:00 | Winner: Rayo Vallecano | ||||
| 1st(1st leg) | Albacete | - | Real Zaragoza | 2:1 (0:0) | ||
| 2nd (2nd leg) | Real Zaragoza | - | Albacete | 1:1 (0:0) | ||
| 1st(1st leg): 08/02/1995 20:00 | 2nd (2nd leg): 15/02/1995 19:15 | Winner: Albacete | ||||
| 1st(1st leg) | UE Lleida | - | Deportivo La Coruña | 0:3 (0:1) | ||
| 2nd (2nd leg) | Deportivo La Coruña | - | UE Lleida | 4:1 (2:1) | ||
| 1st(1st leg): 08/02/1995 20:00 | 2nd (2nd leg): 15/02/1995 20:00 | Winner: Deportivo La Coruña | ||||
| 1st(1st leg) | CD Toledo | - | RCD Mallorca | 1:1 (0:0) | ||
| 2nd (2nd leg) | RCD Mallorca | - | CD Toledo | 2:0 (0:0) | ||
| 1st(1st leg): 08/02/1995 20:00 | 2nd (2nd leg): 15/02/1995 20:00 | Winner: RCD Mallorca | ||||
| 1st(1st leg) | Real Madrid | - | Valencia CF | 1:2 (1:1) | ||
| 2nd (2nd leg) | Valencia CF | - | Real Madrid | 2:1 (0:1) | ||
| 1st(1st leg): 09/02/1995 20:30 | 2nd (2nd leg): 16/02/1995 20:30 | Winner: Valencia CF | ||||
