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| 1st(1st leg) | Sevilla FC | - | Deportivo La Coruña | 2:0 (0:0) | ||
| 2nd (2nd leg) | Deportivo La Coruña | - | Sevilla FC | 3:1 (1:0, 2:0, 2:0) pso | ||
| 1st(1st leg): 08/01/1997 | 2nd (2nd leg): 16/01/1997 | Winner: Deportivo La Coruña | ||||
| 1st(1st leg) | Espanyol Barcelona | - | Sporting Gijón | 4:1 (1:1) | ||
| 2nd (2nd leg) | Sporting Gijón | - | Espanyol Barcelona | 2:2 (0:2) | ||
| 1st(1st leg): 08/01/1997 | 2nd (2nd leg): 15/01/1997 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | Real Oviedo | - | SD Compostela | 1:0 (0:0) | ||
| 2nd (2nd leg) | SD Compostela | - | Real Oviedo | 3:0 (1:0) | ||
| 1st(1st leg): 08/01/1997 | 2nd (2nd leg): 15/01/1997 | Winner: SD Compostela | ||||
| 1st(1st leg) | Granada CF | - | Real Betis | 0:1 (0:1) | ||
| 2nd (2nd leg) | Real Betis | - | Granada CF | 3:0 (3:0) | ||
| 1st(1st leg): 08/01/1997 | 2nd (2nd leg): 15/01/1997 | Winner: Real Betis | ||||
| 1st(1st leg) | CA Osasuna | - | Rayo Vallecano | 3:2 (1:0) | ||
| 2nd (2nd leg) | Rayo Vallecano | - | CA Osasuna | 3:1 (2:0) | ||
| 1st(1st leg): 08/01/1997 | 2nd (2nd leg): 15/01/1997 | Winner: Rayo Vallecano | ||||
| 1st(1st leg) | Real Zaragoza | - | Racing Santander | 1:1 (1:0) | ||
| 2nd (2nd leg) | Racing Santander | - | Real Zaragoza | 1:0 (1:0) | ||
| 1st(1st leg): 08/01/1997 | 2nd (2nd leg): 15/01/1997 | Winner: Racing Santander | ||||
| 1st(1st leg) | Villarreal CF | - | Athletic Bilbao | 0:1 (0:1) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | Villarreal CF | 2:2 (2:1) | ||
| 1st(1st leg): 08/01/1997 | 2nd (2nd leg): 15/01/1997 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | RC Celta | - | CD Logroñés | 2:0 (0:0) | ||
| 2nd (2nd leg) | CD Logroñés | - | RC Celta | 2:2 (0:1) | ||
| 1st(1st leg): 08/01/1997 | 2nd (2nd leg): 15/01/1997 | Winner: RC Celta | ||||
| 1st(1st leg) | Real Madrid | - | Real Valladolid | 2:1 (1:1) | ||
| 2nd (2nd leg) | Real Valladolid | - | Real Madrid | 0:2 (0:0) | ||
| 1st(1st leg): 09/01/1997 | 2nd (2nd leg): 15/01/1997 | Winner: Real Madrid | ||||
| 1st(1st leg) | UE Lleida | - | Hércules CF | 1:0 (1:0) | ||
| 2nd (2nd leg) | Hércules CF | - | UE Lleida | 2:1 (1:1) | ||
| 1st(1st leg): 16/01/1997 | 2nd (2nd leg): 22/01/1997 | Winner: UE Lleida | ||||
