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| 1st(1st leg) | Córdoba CF | - | Deportivo La Coruña | 1:1 (0:1) | ||
| 2nd (2nd leg) | Deportivo La Coruña | - | Córdoba CF | 3:1 (0:0, 1:1) aet | ||
| 1st(1st leg): 21/12/2010 19:00 | 2nd (2nd leg): 05/01/2011 19:00 | Winner: Deportivo La Coruña | ||||
| 1st(1st leg) | FC Barcelona | - | Athletic Bilbao | 0:0 (0:0) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | FC Barcelona | 1:1 (0:0) | ||
| 1st(1st leg): 21/12/2010 19:00 | 2nd (2nd leg): 05/01/2011 21:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Valencia CF | - | Villarreal CF | 0:0 (0:0) | ||
| 2nd (2nd leg) | Villarreal CF | - | Valencia CF | 4:2 (0:2) | ||
| 1st(1st leg): 21/12/2010 21:00 | 2nd (2nd leg): 06/01/2011 17:00 | Winner: Villarreal CF | ||||
| 1st(1st leg) | Atlético Madrid | - | Espanyol Barcelona | 1:0 (1:0) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | Atlético Madrid | 1:1 (0:1) | ||
| 1st(1st leg): 22/12/2010 19:00 | 2nd (2nd leg): 06/01/2011 19:00 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | Real Betis | - | Getafe CF | 1:2 (0:2) | ||
| 2nd (2nd leg) | Getafe CF | - | Real Betis | 1:3 (0:0) | ||
| 1st(1st leg): 22/12/2010 19:00 | 2nd (2nd leg): 06/01/2011 11:00 | Winner: Real Betis | ||||
| 1st(1st leg) | Sevilla FC | - | Málaga CF | 5:3 (2:3) | ||
| 2nd (2nd leg) | Málaga CF | - | Sevilla FC | 0:3 (0:0) | ||
| 1st(1st leg): 22/12/2010 19:00 | 2nd (2nd leg): 05/01/2011 17:00 | Winner: Sevilla FC | ||||
| 1st(1st leg) | UD Almería | - | RCD Mallorca | 4:3 (2:2) | ||
| 2nd (2nd leg) | RCD Mallorca | - | UD Almería | 3:4 (0:4) | ||
| 1st(1st leg): 22/12/2010 19:00 | 2nd (2nd leg): 06/01/2011 15:00 | Winner: UD Almería | ||||
| 1st(1st leg) | Real Madrid | - | Levante UD | 8:0 (4:0) | ||
| 2nd (2nd leg) | Levante UD | - | Real Madrid | 2:0 (0:0) | ||
| 1st(1st leg): 22/12/2010 21:00 | 2nd (2nd leg): 06/01/2011 21:00 | Winner: Real Madrid | ||||
