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| 1st(1st leg) | Albacete | - | Athletic Bilbao | 0:0 (0:0) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | Albacete | 4:0 (1:0) | ||
| 1st(1st leg): 03/01/2012 19:00 | 2nd (2nd leg): 12/01/2012 19:00 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | CD Mirandés | - | Racing Santander | 2:0 (1:0) | ||
| 2nd (2nd leg) | Racing Santander | - | CD Mirandés | 1:1 (1:0) | ||
| 1st(1st leg): 03/01/2012 20:00 | 2nd (2nd leg): 10/01/2012 20:00 | Winner: CD Mirandés | ||||
| 1st(1st leg) | AD Alcorcón | - | Levante UD | 2:1 (1:1) | ||
| 2nd (2nd leg) | Levante UD | - | AD Alcorcón | 4:0 (2:0) | ||
| 1st(1st leg): 03/01/2012 20:00 | 2nd (2nd leg): 11/01/2012 19:00 | Winner: Levante UD | ||||
| 1st(1st leg) | Real Madrid | - | Málaga CF | 3:2 (0:2) | ||
| 2nd (2nd leg) | Málaga CF | - | Real Madrid | 0:1 (0:0) | ||
| 1st(1st leg): 03/01/2012 21:00 | 2nd (2nd leg): 10/01/2012 21:00 | Winner: Real Madrid | ||||
| 1st(1st leg) | Real Sociedad | - | RCD Mallorca | 2:0 (1:0) | ||
| 2nd (2nd leg) | RCD Mallorca | - | Real Sociedad | 6:1 (4:1) | ||
| 1st(1st leg): 04/01/2012 19:00 | 2nd (2nd leg): 10/01/2012 19:00 | Winner: RCD Mallorca | ||||
| 1st(1st leg) | FC Barcelona | - | CA Osasuna | 4:0 (2:0) | ||
| 2nd (2nd leg) | CA Osasuna | - | FC Barcelona | 1:2 (1:0) | ||
| 1st(1st leg): 04/01/2012 21:00 | 2nd (2nd leg): 12/01/2012 21:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Córdoba CF | - | Espanyol Barcelona | 2:1 (0:1) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | Córdoba CF | 4:2 (3:1) | ||
| 1st(1st leg): 05/01/2012 19:00 | 2nd (2nd leg): 11/01/2012 20:00 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | Valencia CF | - | Sevilla FC | 1:0 (1:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | Valencia CF | 2:1 (0:0) | ||
| 1st(1st leg): 05/01/2012 21:00 | 2nd (2nd leg): 11/01/2012 21:00 | Winner: Valencia CF | ||||
