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| 1st(1st leg) | CD Mirandés | - | Athletic Bilbao | 1:2 (0:2) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | CD Mirandés | 6:2 (3:0) | ||
| 1st(1st leg): 31/01/2012 21:00 | 2nd (2nd leg): 07/02/2012 21:00 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | Valencia CF | - | FC Barcelona | 1:1 (1:1) | ||
| 2nd (2nd leg) | FC Barcelona | - | Valencia CF | 2:0 (1:0) | ||
| 1st(1st leg): 01/02/2012 20:00 | 2nd (2nd leg): 08/02/2012 20:00 | Winner: FC Barcelona | ||||
