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| 1st(1st leg) | Atlético Madrid | - | Valencia CF | 4:2 (1:1) | ||
| 2nd (2nd leg) | Valencia CF | - | Atlético Madrid | 0:1 (0:0) | ||
| 1st(1st leg): 19/04/2012 20:05 | 2nd (2nd leg): 26/04/2012 20:05 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | Sporting CP | - | Athletic Bilbao | 2:1 (0:0) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | Sporting CP | 3:1 (2:1) | ||
| 1st(1st leg): 19/04/2012 20:05 | 2nd (2nd leg): 26/04/2012 20:05 | Winner: Athletic Bilbao | ||||
