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| 1st(1st leg) | PFC Ludogorets Razgrad | - | Valencia CF | 0:3 (0:2) | ||
| 2nd (2nd leg) | Valencia CF | - | PFC Ludogorets Razgrad | 1:0 (0:0) | ||
| 1st(1st leg): 13/03/2014 18:00 | 2nd (2nd leg): 20/03/2014 18:00 | Winner: Valencia CF | ||||
| 1st(1st leg) | FC Porto | - | SSC Napoli | 1:0 (0:0) | ||
| 2nd (2nd leg) | SSC Napoli | - | FC Porto | 2:2 (1:0) | ||
| 1st(1st leg): 13/03/2014 18:00 | 2nd (2nd leg): 20/03/2014 20:05 | Winner: FC Porto | ||||
| 1st(1st leg) | FC Basel | - | RB Salzburg | 0:0 (0:0) | ||
| 2nd (2nd leg) | RB Salzburg | - | FC Basel | 1:2 (1:0) | ||
| 1st(1st leg): 13/03/2014 18:00 | 2nd (2nd leg): 20/03/2014 20:05 | Winner: FC Basel | ||||
| 1st(1st leg) | AZ Alkmaar | - | Anzhi Makhachkala | 1:0 (1:0) | ||
| 2nd (2nd leg) | Anzhi Makhachkala | - | AZ Alkmaar | 0:0 (0:0) | ||
| 1st(1st leg): 13/03/2014 20:05 | 2nd (2nd leg): 20/03/2014 17:00 | Winner: AZ Alkmaar | ||||
| 1st(1st leg) | Olympique Lyon | - | Viktoria Plzeň | 4:1 (1:1) | ||
| 2nd (2nd leg) | Viktoria Plzeň | - | Olympique Lyon | 2:1 (0:1) | ||
| 1st(1st leg): 13/03/2014 20:05 | 2nd (2nd leg): 20/03/2014 18:00 | Winner: Olympique Lyon | ||||
| 1st(1st leg) | Sevilla FC | - | Real Betis | 0:2 (0:1) | ||
| 2nd (2nd leg) | Real Betis | - | Sevilla FC | 3:4 (0:1, 0:2, 0:2) pso | ||
| 1st(1st leg): 13/03/2014 20:05 | 2nd (2nd leg): 20/03/2014 20:05 | Winner: Sevilla FC | ||||
| 1st(1st leg) | Tottenham Hotspur | - | SL Benfica | 1:3 (0:1) | ||
| 2nd (2nd leg) | SL Benfica | - | Tottenham Hotspur | 2:2 (1:0) | ||
| 1st(1st leg): 13/03/2014 20:05 | 2nd (2nd leg): 20/03/2014 18:00 | Winner: SL Benfica | ||||
| 1st(1st leg) | Juventus | - | ACF Fiorentina | 1:1 (1:0) | ||
| 2nd (2nd leg) | ACF Fiorentina | - | Juventus | 0:1 (0:0) | ||
| 1st(1st leg): 13/03/2014 20:05 | 2nd (2nd leg): 20/03/2014 18:00 | Winner: Juventus | ||||
