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| 1st(1st leg) | Eintracht Frankfurt | - | Inter | 0:0 (0:0) | ||
| 2nd (2nd leg) | Inter | - | Eintracht Frankfurt | 0:1 (0:1) | ||
| 1st(1st leg): 07/03/2019 17:55 | 2nd (2nd leg): 14/03/2019 20:00 | Winner: Eintracht Frankfurt | ||||
| 1st(1st leg) | Dinamo Zagreb | - | SL Benfica | 1:0 (1:0) | ||
| 2nd (2nd leg) | SL Benfica | - | Dinamo Zagreb | 3:0 (0:0, 1:0) aet | ||
| 1st(1st leg): 07/03/2019 17:55 | 2nd (2nd leg): 14/03/2019 20:00 | Winner: SL Benfica | ||||
| 1st(1st leg) | Sevilla FC | - | Slavia Praha | 2:2 (2:2) | ||
| 2nd (2nd leg) | Slavia Praha | - | Sevilla FC | 4:3 (1:1, 2:2) aet | ||
| 1st(1st leg): 07/03/2019 17:55 | 2nd (2nd leg): 14/03/2019 20:00 | Winner: Slavia Praha | ||||
| 1st(1st leg) | Stade Rennais | - | Arsenal FC | 3:1 (1:1) | ||
| 2nd (2nd leg) | Arsenal FC | - | Stade Rennais | 3:0 (2:0) | ||
| 1st(1st leg): 07/03/2019 17:55 | 2nd (2nd leg): 14/03/2019 20:00 | Winner: Arsenal FC | ||||
| 1st(1st leg) | Zenit St. Petersburg | - | Villarreal CF | 1:3 (1:1) | ||
| 2nd (2nd leg) | Villarreal CF | - | Zenit St. Petersburg | 2:1 (1:0) | ||
| 1st(1st leg): 07/03/2019 17:55 | 2nd (2nd leg): 14/03/2019 20:00 | Winner: Villarreal CF | ||||
| 1st(1st leg) | Chelsea FC | - | Dinamo Kiev | 3:0 (1:0) | ||
| 2nd (2nd leg) | Dinamo Kiev | - | Chelsea FC | 0:5 (0:3) | ||
| 1st(1st leg): 07/03/2019 20:00 | 2nd (2nd leg): 14/03/2019 17:55 | Winner: Chelsea FC | ||||
| 1st(1st leg) | SSC Napoli | - | RB Salzburg | 3:0 (2:0) | ||
| 2nd (2nd leg) | RB Salzburg | - | SSC Napoli | 3:1 (1:1) | ||
| 1st(1st leg): 07/03/2019 20:00 | 2nd (2nd leg): 14/03/2019 17:55 | Winner: SSC Napoli | ||||
| 1st(1st leg) | Valencia CF | - | FK Krasnodar | 2:1 (2:0) | ||
| 2nd (2nd leg) | FK Krasnodar | - | Valencia CF | 1:1 (0:0) | ||
| 1st(1st leg): 07/03/2019 20:00 | 2nd (2nd leg): 14/03/2019 17:55 | Winner: Valencia CF | ||||
