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| 1st(1st leg) | 1. FC Union Berlin | - | Union Saint-Gilloise | 3:3 (1:1) | ||
| 2nd (2nd leg) | Union Saint-Gilloise | - | 1. FC Union Berlin | 3:0 (1:0) | ||
| 1st(1st leg): 09/03/2023 17:45 | 2nd (2nd leg): 16/03/2023 20:00 | Winner: Union Saint-Gilloise | ||||
| 1st(1st leg) | Bayer Leverkusen | - | Ferencvárosi TC | 2:0 (1:0) | ||
| 2nd (2nd leg) | Ferencvárosi TC | - | Bayer Leverkusen | 0:2 (0:1) | ||
| 1st(1st leg): 09/03/2023 17:45 | 2nd (2nd leg): 16/03/2023 20:00 | Winner: Bayer Leverkusen | ||||
| 1st(1st leg) | Sporting CP | - | Arsenal FC | 2:2 (1:1) | ||
| 2nd (2nd leg) | Arsenal FC | - | Sporting CP | 3:5 (1:0, 1:1, 1:1) pso | ||
| 1st(1st leg): 09/03/2023 17:45 | 2nd (2nd leg): 16/03/2023 20:00 | Winner: Sporting CP | ||||
| 1st(1st leg) | AS Roma | - | Real Sociedad | 2:0 (1:0) | ||
| 2nd (2nd leg) | Real Sociedad | - | AS Roma | 0:0 (0:0) | ||
| 1st(1st leg): 09/03/2023 17:45 | 2nd (2nd leg): 16/03/2023 20:00 | Winner: AS Roma | ||||
| 1st(1st leg) | Sevilla FC | - | Fenerbahçe | 2:0 (0:0) | ||
| 2nd (2nd leg) | Fenerbahçe | - | Sevilla FC | 1:0 (1:0) | ||
| 1st(1st leg): 09/03/2023 20:00 | 2nd (2nd leg): 16/03/2023 17:45 | Winner: Sevilla FC | ||||
| 1st(1st leg) | Juventus | - | SC Freiburg | 1:0 (0:0) | ||
| 2nd (2nd leg) | SC Freiburg | - | Juventus | 0:2 (0:1) | ||
| 1st(1st leg): 09/03/2023 20:00 | 2nd (2nd leg): 16/03/2023 17:45 | Winner: Juventus | ||||
| 1st(1st leg) | Manchester United | - | Real Betis | 4:1 (1:1) | ||
| 2nd (2nd leg) | Real Betis | - | Manchester United | 0:1 (0:0) | ||
| 1st(1st leg): 09/03/2023 20:00 | 2nd (2nd leg): 16/03/2023 17:45 | Winner: Manchester United | ||||
| 1st(1st leg) | Shakhtar Donetsk | - | Feyenoord | 1:1 (0:0) | ||
| 2nd (2nd leg) | Feyenoord | - | Shakhtar Donetsk | 7:1 (3:0) | ||
| 1st(1st leg): 09/03/2023 20:00 | 2nd (2nd leg): 16/03/2023 17:45 | Winner: Feyenoord | ||||
