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| 1st(1st leg) | AEK Athen | - | Volos NFC | 4:2 (4:1) | ||
| 2nd (2nd leg) | Volos NFC | - | AEK Athen | 1:0 (1:0) | ||
| 1st(1st leg): 10/02/2021 15:00 | 2nd (2nd leg): 04/03/2021 16:00 | Winner: AEK Athen | ||||
| 1st(1st leg) | PAOK Saloniki | - | Lamia | 5:2 (2:2) | ||
| 2nd (2nd leg) | Lamia | - | PAOK Saloniki | 1:1 (0:1) | ||
| 1st(1st leg): 10/02/2021 17:00 | 2nd (2nd leg): 03/03/2021 16:00 | Winner: PAOK Saloniki | ||||
| 1st(1st leg) | Olympiakos Piraeus | - | Aris Saloniki | 2:1 (2:1) | ||
| 2nd (2nd leg) | Aris Saloniki | - | Olympiakos Piraeus | 1:1 (0:0) | ||
| 1st(1st leg): 10/02/2021 19:30 | 2nd (2nd leg): 04/03/2021 18:00 | Winner: Olympiakos Piraeus | ||||
| 1st(1st leg) | PAS Giannina | - | Panathinaikos | 2:1 (1:1) | ||
| 2nd (2nd leg) | Panathinaikos | - | PAS Giannina | 1:2 (0:2) | ||
| 1st(1st leg): 18/02/2021 13:00 | 2nd (2nd leg): 03/03/2021 18:00 | Winner: PAS Giannina | ||||
