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| 1st(1st leg) | AS Roma | - | SSC Napoli | 1:0 (0:0) | ||
| 2nd (2nd leg) | SSC Napoli | - | AS Roma | 3:2 (1:2) | ||
| 1st(1st leg): 30/10/1991 | 2nd (2nd leg): 29/11/1991 19:30 | Winner: AS Roma | ||||
| 1st(1st leg) | Pisa SC | - | Genoa CFC | 2:0 (1:0) | ||
| 2nd (2nd leg) | Genoa CFC | - | Pisa SC | 4:0 (2:0) | ||
| 1st(1st leg): 30/10/1991 13:30 | 2nd (2nd leg): 04/12/1991 19:30 | Winner: Genoa CFC | ||||
| 1st(1st leg) | Sampdoria | - | AS Bari | 1:1 (0:1) | ||
| 2nd (2nd leg) | AS Bari | - | Sampdoria | 2:2 (0:0, 1:1) aet | ||
| 1st(1st leg): 30/10/1991 19:30 | 2nd (2nd leg): 04/12/1991 19:30 | Winner: Sampdoria | ||||
| 1st(1st leg) | Parma AC | - | ACF Fiorentina | 0:0 (0:0) | ||
| 2nd (2nd leg) | ACF Fiorentina | - | Parma AC | 1:1 (1:0) | ||
| 1st(1st leg): 30/10/1991 19:30 | 2nd (2nd leg): 04/12/1991 17:00 | Winner: Parma AC | ||||
| 1st(1st leg) | Hellas Verona | - | AC Milan | 2:2 (1:2) | ||
| 2nd (2nd leg) | AC Milan | - | Hellas Verona | 1:1 (1:0) | ||
| 1st(1st leg): 30/10/1991 19:30 | 2nd (2nd leg): 11/12/1991 | Winner: AC Milan | ||||
| 1st(1st leg) | Torino FC | - | Lazio Roma | 2:0 (2:0) | ||
| 2nd (2nd leg) | Lazio Roma | - | Torino FC | 0:0 (0:0) | ||
| 1st(1st leg): 30/10/1991 19:30 | 2nd (2nd leg): 04/12/1991 19:30 | Winner: Torino FC | ||||
| 1st(1st leg) | Atalanta | - | Juventus | 0:0 (0:0) | ||
| 2nd (2nd leg) | Juventus | - | Atalanta | 3:1 (1:1) | ||
| 1st(1st leg): 30/10/1991 19:30 | 2nd (2nd leg): 05/11/1991 | Winner: Juventus | ||||
| 1st(1st leg) | Inter | - | Calcio Como | 2:2 (2:0) | ||
| 2nd (2nd leg) | Calcio Como | - | Inter | 1:2 (0:1) | ||
| 1st(1st leg): 30/10/1991 19:30 | 2nd (2nd leg): 04/12/1991 19:30 | Winner: Inter | ||||
