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| 1st(1st leg) | Lazio Roma | - | Modena FC | 5:0 (2:0) | ||
| 2nd (2nd leg) | Modena FC | - | Lazio Roma | 1:4 (1:1) | ||
| 1st(1st leg): 30/08/1994 | 2nd (2nd leg): 21/09/1994 | Winner: Lazio Roma | ||||
| 1st(1st leg) | US Fiorenzuola | - | AS Roma | 0:3 (0:1) | ||
| 2nd (2nd leg) | AS Roma | - | US Fiorenzuola | 2:1 (1:0) | ||
| 1st(1st leg): 31/08/1994 16:45 | 2nd (2nd leg): 22/09/1994 19:30 | Winner: AS Roma | ||||
| 1st(1st leg) | AC Milan | - | US Palermo | 0:1 (0:1) | ||
| 2nd (2nd leg) | US Palermo | - | AC Milan | 2:3 (0:1, 0:1, 0:1) pso | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: AC Milan | ||||
| 1st(1st leg) | Calcio Padova | - | Inter | 0:3 (0:1) | ||
| 2nd (2nd leg) | Inter | - | Calcio Padova | 0:1 (0:1) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: Inter | ||||
| 1st(1st leg) | Calcio Como | - | US Foggia | 0:2 (0:1) | ||
| 2nd (2nd leg) | US Foggia | - | Calcio Como | 5:0 (2:0) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: US Foggia | ||||
| 1st(1st leg) | Cagliari Calcio | - | Atalanta | 1:0 (0:0) | ||
| 2nd (2nd leg) | Atalanta | - | Cagliari Calcio | 2:1 (1:1) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: Cagliari Calcio | ||||
| 1st(1st leg) | Parma AC | - | AC Perugia | 4:0 (4:0) | ||
| 2nd (2nd leg) | AC Perugia | - | Parma AC | 1:0 (1:0) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: Parma AC | ||||
| 1st(1st leg) | Udinese Calcio | - | ACF Fiorentina | 2:2 (2:2) | ||
| 2nd (2nd leg) | ACF Fiorentina | - | Udinese Calcio | 2:0 (0:0) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: ACF Fiorentina | ||||
| 1st(1st leg) | Sampdoria | - | Vicenza Calcio | 5:1 (2:0) | ||
| 2nd (2nd leg) | Vicenza Calcio | - | Sampdoria | 2:1 (1:0) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: Sampdoria | ||||
| 1st(1st leg) | AS Bari | - | Piacenza Calcio | 0:1 (0:0) | ||
| 2nd (2nd leg) | Piacenza Calcio | - | AS Bari | 1:1 (0:0) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: Piacenza Calcio | ||||
| 1st(1st leg) | SSC Napoli | - | AS Fidelis Andria | 3:2 (1:0) | ||
| 2nd (2nd leg) | AS Fidelis Andria | - | SSC Napoli | 1:1 (1:0) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: SSC Napoli | ||||
| 1st(1st leg) | US Cremonese | - | US Lecce | 1:1 (1:0) | ||
| 2nd (2nd leg) | US Lecce | - | US Cremonese | 2:2 (0:0, 1:1) aet | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: US Cremonese | ||||
| 1st(1st leg) | AC Cesena | - | Genoa CFC | 0:1 (0:0) | ||
| 2nd (2nd leg) | Genoa CFC | - | AC Cesena | 2:0 (1:0) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: Genoa CFC | ||||
| 1st(1st leg) | AC Reggiana | - | Brescia Calcio | 1:0 (1:0) | ||
| 2nd (2nd leg) | Brescia Calcio | - | AC Reggiana | 0:2 dec. | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: AC Reggiana | ||||
| 1st(1st leg) | Juventus | - | Chievo Verona | 0:0 (0:0) | ||
| 2nd (2nd leg) | Chievo Verona | - | Juventus | 1:3 (0:2) | ||
| 1st(1st leg): 31/08/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: Juventus | ||||
| 1st(1st leg) | AC Monza | - | Torino FC | 0:1 (0:0) | ||
| 2nd (2nd leg) | Torino FC | - | AC Monza | 4:2 (1:1) | ||
| 1st(1st leg): 01/09/1994 19:30 | 2nd (2nd leg): 21/09/1994 | Winner: Torino FC | ||||
